• 专利标题:   Interlayer modification of fiber-reinforced composite material comprises e.g. mixing and heating graphene oxide, amino-terminated silicone oil, amino-containing silane coupling agent and reaction solvent through heater, and reacting to obtain modified graphene oxide.
  • 专利号:   CN116144051-A
  • 发明人:   WU L, WANG J
  • 专利权人:   NINGBO BEILUN ZHONGKE HAIXI IND TECHNOLO
  • 国际专利分类:   B29C070/34, C08J005/04, C08K003/04, C08K007/04, C08K007/06, C08K007/14, C08K009/06, C08L001/02, C08L061/06, C08L063/00, C08L079/04
  • 专利详细信息:   CN116144051-A 23 May 2023 C08J-005/04 202353 Chinese
  • 申请详细信息:   CN116144051-A CN10048609 31 Jan 2023
  • 优先权号:   CN10048609

▎ 摘  要

NOVELTY - Interlayer modification of fiber reinforced composite material comprises (i) mixing and heating graphene oxide, amino-terminated silicone oil, amino-containing silane coupling agent and reaction solvent through heater, reacting at 150℃ for 13 hours to obtain modified graphene oxide, and mixing and stirring modified graphene oxide, carbon black oxide and organic solvent through stirrer to make binary nanocomposite reinforced phase slurry, (ii) mixing binary nano composite reinforced slurry with matrix resin to obtain first mixed material, removing organic solvent in the first mixture, mixing with curing agent to obtain second mixture, and (iii) coating second mixture on the surface of at least two layers of fiber-reinforced composite material sub-layers, laminating and curing the at least two layers of fiber-reinforced composite material sub-layers to obtain layer intermodified fiber reinforced composites. USE - The method is useful for interlayer modification of fiber reinforced composite material e.g. glass fiber, carbon fiber, aramid fiber and base material. ADVANTAGE - The method enables controlling the feeding device to feed in time when the raw material amount is not enough, so as to ensure stirrer can maintain normal work and improves the stirring efficiency. DETAILED DESCRIPTION - Interlayer modification of fiber reinforced composite material comprises (i) mixing and heating graphene oxide, amino-terminated silicone oil, amino-containing silane coupling agent and reaction solvent through heater, reacting at 150℃ for 13 hours to obtain modified graphene oxide, where reaction solvent is benzene, toluene or xylene, and mixing and stirring modified graphene oxide, carbon black oxide and organic solvent through stirrer to make binary nanocomposite reinforced phase slurry, (ii) mixing binary nano composite reinforced slurry with matrix resin to obtain first mixed material, removing organic solvent in the first mixture, mixing with curing agent to obtain second mixture, and (iii) coating second mixture on the surface of at least two layers of fiber-reinforced composite material sub-layers, laminating and curing the at least two layers of fiber-reinforced composite material sub-layers to obtain layer intermodified fiber reinforced composites, where the organic solvent comprises dimethylformamide, acetone and/or tetrahydrofuran, the matrix resin comprises epoxy resin, phenolic resin and/or cyanate resin, the curing agent comprises polyamide 650 and/or polyamide curing agent EPIKURE3140A, and the fiber-reinforced composite material comprises carbon fiber-reinforced composite material, glass fiber-reinforced composite material, ceramic fiber-reinforced composite material and/or flax fiber-reinforced composite material.