• 专利标题:   Graphene/silicon oxide-coated nano-silicon composite useful as cathode material for lithium ion battery comprises nano-silicon matrix, silicon oxide coating layer coated on surface of nano-silicon substrate and graphene coating layer coated on surface of silicon oxide coating layer.
  • 专利号:   CN114242961-A
  • 发明人:   CHEN C, CHEN W, XIONG W, HUANG S, DU B, YANG P, ZHOU T, YE S, ZHANG Q, LI L, YANG Y, LIU J
  • 专利权人:   SHENZHEN EIGEN EQUATION GRAPHENE TECHNOL
  • 国际专利分类:   B82Y030/00, H01M010/0525, H01M004/36, H01M004/38, H01M004/62
  • 专利详细信息:   CN114242961-A 25 Mar 2022 H01M-004/36 202237 Chinese
  • 申请详细信息:   CN114242961-A CN11292379 03 Nov 2021
  • 优先权号:   CN11292379

▎ 摘  要

NOVELTY - Graphene/silicon oxide-coated nano-silicon composite comprises nano-silicon matrix, silicon oxide coating layer coated on the surface of the nano-silicon substrate and the graphene coating layer coated on the surface of the silicon oxide coating layer. USE - The oxide-coated nano-silicon composite material of graphene/silicon is useful as cathode material for lithium ion battery (claimed). ADVANTAGE - The graphene/silicon oxide-coated nano-silicon composite material has higher specific capacity, rate performance and cycle stability. The method is simple and economical and has easy industrial production. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing graphene/silicon oxide-coated nano-silicon composite comprising providing silicon oxide-coated nano-silicon, mixing the silicon oxide-coated nano-silicon with an organic solvent to obtain a suspension, adding monolayer graphene aqueous solution of edge oxidation to suspension, obtaining oxide-coated nano-silicon composite material of edge-oxidized graphene/silicon through stirring, heating and drying, thermally treating the edge-oxidized graphene/silicon oxide-coated nano-silicon composite and obtaining graphene/silicon oxide-coated nano-silicon composite material. The preparation of silicon oxide-coated nano-silicon specifically includes mixing micro-silicon with organic solvent to obtain a mixed solution and preparing the silicon oxide-coated nano-silicon after the mixed solution is subjected to high-energy ball milling.