• 专利标题:   Graphene-coated catalyst useful for encapsulating iron carbide particles and synthesizing gas to prepare low-carbon olefin, comprises glucose as a carbon source, ferric nitrate as an iron source, and potassium as an auxiliary agent.
  • 专利号:   CN112517034-A
  • 发明人:   WANG C, TIAN Z, CHEN L, WEN C, ZHANG X, LIU Q, MA L
  • 专利权人:   GUANGZHOU ENERGY INST CONVERSION CHINESE
  • 国际专利分类:   B01J027/22, B01J037/08, B01J037/18, C07C001/04, C07C011/04, C07C011/06, C07C011/08
  • 专利详细信息:   CN112517034-A 19 Mar 2021 B01J-027/22 202134 Pages: 11 Chinese
  • 申请详细信息:   CN112517034-A CN10879943 18 Sep 2019
  • 优先权号:   CN10879943

▎ 摘  要

NOVELTY - Graphene-coated catalyst comprises glucose as a carbon source, ferric nitrate as an iron source, and potassium as an auxiliary agent, and forms a graphene-coated core-shell structure of iron carbide-coated iron carbide through pyrolysis and carbonization processes at high temperatures. The content of iron is 10-40 wt.%, and potassium adjuvant is 0.5-5 wt.%. The preparation method includes sequentially dissolving ferric nitrate and glucose in deionized water, the mass ratio of ferric nitrate to glucose is 1:5-1:1 respectively, adding potassium nitrate as an auxiliary agent, and continuously stirring to form a light yellow solution, heating to 75-85 degrees to evaporate the solvent, and drying overnight in an oven at 60 degrees C to obtain a brown-black viscous foamy substance, which is the iron-glucose precursor, calcining the iron-glucose precursor at 700-900 degrees C for 1-3 hours in a flowing nitrogen atmosphere, the heating rate used is 1-3 degrees C/minute. USE - The catalyst is useful for encapsulating iron carbide particles and synthesizing gas to prepare low-carbon olefin. ADVANTAGE - The catalyst has good catalyst stability and strong electronic effect, and high reaction activity.