• 专利标题:   Reduction of graphene oxide used for gene medicine carrier, comprises reacting diisocyanate modified amphiphilic polymer and graphene oxide in organic solvent, and washing solid product using organic solvent to obtain target product.
  • 专利号:   CN102424381-A, CN102424381-B
  • 发明人:   CHENG G, KONG T, LI N, QI L, SONG Q, SU R, TANG M, ZHANG Q
  • 专利权人:   SUZHOU INST NANOTECH NANOBIONICS
  • 国际专利分类:   B82Y040/00, C01B031/04
  • 专利详细信息:   CN102424381-A 25 Apr 2012 C01B-031/04 201252 Pages: 8 Chinese
  • 申请详细信息:   CN102424381-A CN10267832 09 Sep 2011
  • 优先权号:   CN10267832

▎ 摘  要

NOVELTY - Reduction of graphene oxide comprises reacting diisocyanate modified amphiphilic polymer and graphene oxide at mass ratio of 1000:1-1:1000, in organic solvent at 50-200 degrees C for 0.1-120 hours, separating solid product from reaction mixture and fully washing solid product using organic solvent to obtain target product reduced graphene, with diisocyanate modified amphiphilic polymer obtained from reaction of amphiphilic polymer and diisocyanate. USE - Method for reducing graphene oxide (claimed) used for gene medicine carrier, biosensor and composite material. ADVANTAGE - The method is simple, and has low cost; and the prepared reduced graphene is with good conductivity, wide stable dispersing solvent range and good biocompatibility. DETAILED DESCRIPTION - Reduction of graphene oxide comprises reacting diisocyanate modified amphiphilic polymer and graphene oxide at mass ratio of 1000:1-1:1000, in organic solvent at 50-200 degrees C for 0.1-120 hours, separating solid product from reaction mixture and fully washing solid product using organic solvent to obtain target product reduced graphene, with diisocyanate modified amphiphilic polymer obtained from reaction of amphiphilic polymer and diisocyanate. The diisocyanate is toluene diisocyanate, hexamethylene diisocyanate, 4,4'-methylene benzene diisocyanate, isophorone diisocyanate, trimethyl diisocyanate, dicyclohexyl methane diisocyanate and p-phenylene diisocyanate; the amphiphilic polymer is polyethylene glycol, monomethyl polyethylene glycol, Tween (RTM: polyoxyethylene sorbitan fatty acid ester), Triton (RTM: surface-active polyoxyethylene ether), p-octyl phenol polyoxyethylene ether, sorbitol aliphatic ester and polypropylene ether; and the organic solvent is N,N-dimethyl formamide (DMF), dimethylsulfoxide (DMSO) and N-methyl-2-pyrrolidone (NMP).