• 专利标题:   Nitrogen-doped graphene coated nano-sulfur anode composite material, used in making lithium-sulfur batteries, comprises three-dimensional conductive network formed by nitrogen-doped graphene, and nitrogen-doped graphene sheets.
  • 专利号:   WO2015188726-A1, CN105244476-A, KR2017003646-A, EP3157080-A1, IN201637038905-A, US2017125800-A1, JP2017521847-W, EP3157080-A4, JP6360252-B2, EP3157080-B1, US10439213-B2
  • 发明人:   HOU Y, LI G, LI H, LI W, LIU M, QIU Y, YE F, ZHANG Y, ZHOU L
  • 专利权人:   CHINESE ACAD SCI SUZHOU NANOTECH NANO, SUZHOU INST NANOTECH NANOBIONICS, CHINESE ACAD SCI SUZHOU NANOTECH NANO, CHINESE ACAD SCI SUZHOU NANOTECH NANO, CHINESE ACAD SCI SUZHOU NANOTECH NANO
  • 国际专利分类:   H01M004/36, H01M010/05, H01M010/052, H01M004/13, H01M004/38, B01J013/08, H01M004/58, H01M004/587, C01B032/184, H01M004/136, H01M004/02, H01M004/62, H01M004/00
  • 专利详细信息:   WO2015188726-A1 17 Dec 2015 H01M-004/36 201602 Pages: 25 Chinese
  • 申请详细信息:   WO2015188726-A1 WOCN080885 05 Jun 2015
  • 优先权号:   CN10256653, WOCN080885

▎ 摘  要

NOVELTY - Nitrogen-doped graphene coated nano-sulfur anode composite material, comprises a three-dimensional conductive network formed by nitrogen-doped graphene overlapped with each other, and nitrogen-doped graphene sheets wrapped uniformly with nano-sulfur particles. USE - The nitrogen-doped graphene coated nano-sulfur anode composite material is useful in making lithium-sulfur batteries (claimed). ADVANTAGE - The nitrogen-doped graphene coated nano-sulfur anode composite material: provides the lithium-sulfur battery having a discharge capacity rate at 0.2C of greater than or equal to 1200 mAh.g-1, a discharge capacity rate at 1C of greater than or equal to 1000 mAh.g-1, a discharge capacity rate at 2C of greater than or equal to 800 mAh.g-1, a discharge capacity rate at 5C of greater than or equal to 600 mAh.g-1, a rate at 2C of less than or equal to 2000 cycles, and a decay capacity rate of less than or equal to 0.028% for each cycle; is free of conductive additive (all claimed); exhibits high capacity, high cycle stability, high rate performance and high conductivity; and inhibits the dissolution and shuttle effects of lithium-sulfur batteries. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) preparing the nitrogen-doped graphene coated nano-sulfur anode composite material, comprising dispersing the nitrogen-doped graphene in a liquid phase reaction system containing at least a sulfur source and acid, and depositing nano-sulfur particles by in situ chemical reaction of sulfur source and the acid to prepare the nitrogen-doped graphene coated nano-sulfur composites; and (2) a lithium-sulfur battery, comprising an anode, a cathode and an electrolyte, where the anode is the nitrogen-doped graphene coated nano-sulfur anode composite material.