• 专利标题:   High intensity orderly arranged porous graphene fiber, useful for loading various types of catalysts, and as lightweight wire, prepared by e.g. reacting graphite and sulfuric acid, filtering, drying, stirring, and ultrasonically treating.
  • 专利号:   CN102586946-A, CN102586946-B
  • 发明人:   GAO C, XU Z
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   D01D001/02, D01D005/04, D01F011/16, D01F009/08
  • 专利详细信息:   CN102586946-A 18 Jul 2012 D01F-009/08 201267 Pages: 5 Chinese
  • 申请详细信息:   CN102586946-A CN10001524 05 Jan 2012
  • 优先权号:   CN10001524

▎ 摘  要

NOVELTY - High intensity orderly arranged porous graphene fiber is claimed. The preparation of porous graphene fiber comprises: (i) reacting e.g. graphite and sulfuric acid, cooling, diluting by deionized water, filtering, washing, and naturally drying; (ii) stirring intercalated graphite, magnesium sulfate and potassium permanganate, adding deionized water and hydrogen peroxide, and drying; (iii) ultrasonically treating graphite oxide; (iv) extruding graphene oxide spinning liquid crystal sol, condensing, and performing freeze drying or critical freezing drying; and (v) reducing fiber, and drying. USE - The fiber is useful for loading various types of catalysts, and as a lightweight wire. ADVANTAGE - The fiber has low density, high mechanical property, and good flexibility. DETAILED DESCRIPTION - High intensity orderly arranged porous graphene fiber is claimed. The preparation of high intensity orderly arranged porous graphene fiber comprises: (i) reacting (in parts by wt.) graphite raw material (1), sulfuric acid (1-100), potassium sulfate (0.5-5) and phosphorus pentoxide (0.5-5) for 1-10 hours at 25-100 degrees C, cooling to room temperature, diluting by using deionized water, filtering by a filter film, washing with deionized water till the solution is neutral, and naturally drying for 10-50 hours to obtain an intercalated graphite; (ii) stirring (in parts by wt.) intercalated graphite (1), magnesium sulfate (1-100) and potassium permanganate (0.5-10) for 0.1-10 hours at -10 degrees C to 50 degrees C, adding (in parts by wt.) deionized water (10-2000) and hydrogen peroxide (0.1-10), and reacting for 0.1-10 hours, filtering by the filter film, repeatedly washing by using deionized water till the solution is neutral, and naturally drying to obtain graphite oxide; (iii) dissolving graphite oxide in water (5-100 parts by wt.), and ultrasonically treating at 0-50 KHz for 0.1-10 hours to obtain a graphene oxide spinning liquid crystal sol; (iv) extruding the obtained graphene oxide spinning liquid crystal sol in liquid nitrogen at a speed of 1-100 ml/hour, where the diameter of a spinning capillary is 50-500 mu m, allowing to stand for 50 seconds, condensing, then carrying out freeze drying or critical freezing drying for 2-40 hours, and finally obtaining the orderly arranged porous graphene fiber; and (v) reducing the graphene oxide fiber of the step (iv) with a reducing agent for 0.1-100 hours, washing, and drying to obtain the product,.