• 专利标题:   Preparing reduced graphene/amination column arene/sulfur as lithium-sulfur cathode material involves taking graphene oxide solution and adding 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride salt and N-hydroxysuccinimide.
  • 专利号:   CN111740093-A
  • 发明人:   DIAO G, ZHANG H, NI L, CUI Y, ZHA J, WU R
  • 专利权人:   UNIV YANGZHOU
  • 国际专利分类:   C01B032/19, C01B032/194, H01M010/052, H01M004/38, H01M004/62
  • 专利详细信息:   CN111740093-A 02 Oct 2020 H01M-004/38 202088 Pages: 7 Chinese
  • 申请详细信息:   CN111740093-A CN10527373 11 Jun 2020
  • 优先权号:   CN10527373

▎ 摘  要

NOVELTY - Preparing reduced graphene/amination column (5) arene/sulfur involves taking graphene oxide solution and adding 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride salt and N-hydroxysuccinimide, stirring for more than 30 minutes, and then adding amination column (5) aromatic hydrocarbon, stirring for 0.5-1 hours, raising temperature to certain temperature and keeping constant, then taking reaction product and dialyzing to obtain GO-AP(5) supramolecular graphene composite material. The reduced graphene/amination column (5) aromatic hydrocarbon/sulfur is used as lithium-sulfur cathode material. The ascorbic acid is added as reducing agent to the obtained GO-AP(5) supramolecular graphene composite material, and stirred at room temperature for more than 2 hours. The concentrated hydrochloric acid is added, and sodium thiosulfate aqueous solution is added dropwise, slowly stirred for more than 6 hours. USE - Method for preparing reduced graphene/amination column arene/sulfur as lithium-sulfur cathode material. ADVANTAGE - The method enables to prepare reduced graphene/amination column arene/sulfur that has high capacity, good rate and long cycle life. DETAILED DESCRIPTION - Preparing reduced graphene/amination column (5) arene/sulfur as lithium-sulfur cathode material involves taking graphene oxide solution and adding 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride salt and N-hydroxysuccinimide, stirring for more than 30 minutes, and then adding amination column (5) aromatic hydrocarbon, stirring for 0.5-1 hours, raising temperature to certain temperature and keeping constant, then taking reaction product and dialyzing to obtain GO-AP(5) supramolecular graphene composite material. The reduced graphene/amination column (5) aromatic hydrocarbon/sulfur is used as lithium-sulfur cathode material. The ascorbic acid is added as reducing agent to the obtained GO-AP(5) supramolecular graphene composite material, and stirred at room temperature for more than 2 hours. The concentrated hydrochloric acid is added, and sodium thiosulfate aqueous solution is added dropwise, slowly stirred for more than 6 hours. The concentrated hydrochloric acid and sodium thiosulfate are reacted to generate elemental sulfur, and liquid is collected and centrifuged to obtain cathode material.