• 专利标题:   Preparing transition metal-graphene composite material used in lithium ion battery and supercapacitor material, involves dispersing nanosheets of transition metal compound by mixing in solvent to obtain dispersed material.
  • 专利号:   CN104269514-A, CN104269514-B
  • 发明人:   ZENG H, JIANG L
  • 专利权人:   UNIV NANJING AERONAUTICS ASTRONAUTICS
  • 国际专利分类:   B82Y030/00, C01B031/04, C01G039/06, H01G011/26, H01M004/13, H01M004/139
  • 专利详细信息:   CN104269514-A 07 Jan 2015 H01M-004/13 201519 Pages: 16 Chinese
  • 申请详细信息:   CN104269514-A CN10420320 25 Aug 2014
  • 优先权号:   CN10420320

▎ 摘  要

NOVELTY - Preparing transition metal-graphene composite material involves dispersing nanosheets of transition metal compound by mixing in solvent to obtain transition metal compound nanosheet dispersed material. The dispersed material is added with graphene oxide solution and then the obtained material is mixed with a mixed solvent of isopropyl alcohol and water, where the total mass of transition metal compound nanosheets and graphene oxide is 5-90 wt.%. The obtained mixed solution is added to a reaction vessel and then heating at 180-240 degrees C. USE - Method for preparing transition metal-graphene composite material (claimed) used in lithium ion battery and supercapacitor material. ADVANTAGE - The method enables to prepare transition metal-graphene composite material in simple and reproducible manner, and has improved contact between the active material and electrolyte. DETAILED DESCRIPTION - Preparing transition metal-graphene composite material involves dispersing nanosheets of transition metal compound by mixing in solvent to obtain transition metal compound nanosheet dispersed material. The dispersed material is added with graphene oxide solution and then the obtained material is mixed with a mixed solvent of isopropyl alcohol and water, where the total mass of transition metal compound nanosheets and graphene oxide is 5-90 wt.%. The obtained mixed solution is added to a reaction vessel and then heating at 180-240 degrees C. The heated material is performed a hydrothermal reaction for 16-42 hours and then the obtained material is cooled to room temperature after finishing reaction to obtain a cylindrical hydrogel. The hydrogel is added with hydrazine hydrate solution and then the obtained material is heated at 80-100 degrees C for 8-24 hours. The heated material is cooled to -80 degrees C and then the cooled material is dried under vacuum to obtain the desired product.