• 专利标题:   Preparation of graphene-supported cerium oxide-rubber composite material used in preparation of radiation-shield cover, involves mixing graphene-supported cerium oxide and natural rubber-styrene butadiene rubber, and vulcanizing.
  • 专利号:   CN107434857-A
  • 发明人:   LI P, WANG Z, LI L, ZHAO P, YANG Z, LI Y, CHENG Y, LI S
  • 专利权人:   UNIV GUANGDONG OCEAN
  • 国际专利分类:   C08K003/22, C08K009/12, C08L007/00, C08L009/06
  • 专利详细信息:   CN107434857-A 05 Dec 2017 C08L-007/00 201802 Pages: 10 Chinese
  • 申请详细信息:   CN107434857-A CN10730174 23 Aug 2017
  • 优先权号:   CN10730174

▎ 摘  要

NOVELTY - Preparation of graphene-supported cerium oxide-rubber composite material involves dissolving graphene oxide in water, obtaining graphene solution with concentration of 0.1-2 mg/ml, dissolving cerium nitrate in water, adding resultant cerium nitrate solution to graphene oxide solution, stirring, adjusting pH to 8-14 using aqueous ammonia, calcining at 80-220 degrees C for 8-48 hours, cooling, washing with water and ethanol, drying at 60-100 degrees C for 20-30 hours, obtaining graphene-supported cerium oxide, mixing resultant product and natural rubber-styrene butadiene rubber, and vulcanizing. USE - Preparation of graphene-supported cerium oxide-rubber composite material used in preparation of radiation-shield cover (all claimed). ADVANTAGE - The method enables preparation of graphene-supported cerium oxide-rubber composite material having improved electron transfer rate, excellent electromagnetic shielding effect, aging resistance, mechanical property, flexibility and oxidation resistance. DETAILED DESCRIPTION - Preparation of graphene-supported cerium oxide-rubber composite material involves dissolving graphene oxide in water, obtaining graphene solution with concentration of 0.1-2 mg/ml, dissolving cerium nitrate in water, adding resultant cerium nitrate solution to graphene oxide solution, stirring for 60-210 minutes, leaving still at room temperature for 10-15 hours, adjusting pH to 8-14 using aqueous ammonia, adding resultant product to a hydrothermal synthesis reactor, calcining at 80-220 degrees C for 8-48 hours, cooling to room temperature, washing with water and ethanol, drying at 60-100 degrees C for 20-30 hours, obtaining graphene-supported cerium oxide, mixing resultant product and natural rubber-styrene butadiene rubber, and vulcanizing in a flat vulcanizing machine. The mass ratio of cerium nitrate and graphene oxide is 40-60:1.