• 专利标题:   Preparation of graphene oxide permeable membrane used for e.g. emergency water bag, involves mixing graphene oxide and additive, adding polysulfone, defoaming to get polysulfone casting solution and dispersing casting solution on cloth.
  • 专利号:   CN105032207-A, CN105032207-B
  • 发明人:   PAN H, SHENG J, XUE L, ZHANG A, ZHAO X
  • 专利权人:   NINGBO LIANHUA ENVIRONMENTAL PROTECTION, CHINESE ACAD SCI NINGBO INST MATERIAL, NINGBO INST MATERIALS TECHNOLOGY ENG C, NINGBO LIANHUA ENVIRONMENTAL PROTECTION
  • 国际专利分类:   B01D067/00, B01D071/02, B01D071/06, B01D071/68
  • 专利详细信息:   CN105032207-A 11 Nov 2015 B01D-071/02 201613 Pages: 9 English
  • 申请详细信息:   CN105032207-A CN10474540 05 Aug 2015
  • 优先权号:   CN10474540

▎ 摘  要

NOVELTY - The preparation method of graphene oxide permeable membrane involves adding graphene oxide and organic additive to a container, adding solvent, stirring, adding polysulfone, stirring for 12-24 hours, carrying out defoaming reaction to obtain graphene oxide dispersed polysulfone casting solution, ultrasonically dispersing cyclodextrin and graphene oxide in distilled water to prepare cyclodextrin/graphene oxide aqueous solution, dispersing polysulfone casting liquid on non-woven cloth, and soaking cloth in coagulating bath. USE - Preparation of graphene oxide permeable membrane used for emergency water bag, plant protection box and sea water desalination system, and for softening of hard water and industrial waste water. ADVANTAGE - The method enables preparation of graphene oxide permeable membrane that has high mechanical strength, solvent resistance, water flux and salt rejection rate, and is environmentally-friendly. DETAILED DESCRIPTION - The preparation method of graphene oxide permeable membrane, involves adding 0.1-1 %mass graphene oxide and 0.1-8 %mass organic additive to a container, stirring at room temperature for 12-24 hours, adding 59-90 %mass solvent, stirring for 0.1-5 hours, adding 10-30 %mass polysulfone at 30-100 degrees C, stirring for 12-24 hours, carrying out defoaming reaction at 30-80 degrees C for 5 hours to obtain graphene oxide-dispersed polysulfone casting solution, ultrasonically dispersing cyclodextrin and graphene oxide in distilled water at 20-100 kHz and 25-90 degrees C for 0.1-5 hours to obtain cyclodextrin/graphene oxide aqueous solution containing 0.05-5 %mass cyclodextrin and 0.05-1 %mass graphene oxide, dissolving benzoyl chloride in n-hexane to obtain 0.05-5 %mass benzoyl chloride-hexane solution, uniformly dispersing the polysulfone casting liquid on non-woven cloth with 10-180 mu m thickness, soaking cloth in coagulating bath of deionized water at 5-30 degrees C, removing the residual solvent with deionized water to obtain polysulfone ultrafiltration membrane, immersing the polysulfone ultrafiltration membrane in cyclodextrin/graphene oxide aqueous solution for 1-8 minutes, soaking membrane in benzoyl chloride-hexane solution for 0.5-5 minutes and curing at 60-150 degrees C for 2-15 minutes.