• 专利标题:   Method for improving stability of graphite or graphene cathode of potassium ion battery, involves adjusting coordination of solvent molecule and potassium hexafluorophosphate (KPF6), and forming stable and uniform organic-rich passivation layer on graphite or graphene cathode surface.
  • 专利号:   CN113471428-A
  • 发明人:   LU B, GU M
  • 专利权人:   FUJIAN STRAIT GRAPHENE IND TECHNOLOGY
  • 国际专利分类:   H01M010/0563, H01M010/054, H01M004/583
  • 专利详细信息:   CN113471428-A 01 Oct 2021 H01M-004/583 202190 Chinese
  • 申请详细信息:   CN113471428-A CN10550953 20 May 2021
  • 优先权号:   CN10550953

▎ 摘  要

NOVELTY - The method involves using lithium hexafluorophosphate as electrolyte, graphite or graphene as negative electrode of potassium ion battery for pre-circulating treatment at 50degreesC high temperature. The coordination of the solvent molecule and KPF6 is adjusted. A stable and uniform organic-rich passivation layer is formed on the graphite or graphene cathode surface. The 1M lithium hexafluorophosphate is set to use ethylene glycol dimethyl ether and ethylene carbonate as the solvent, KPF6 as the solute, and the volume ratio of the solvent is 1:1. The charge-discharge cycle treatment is performed 3-15 times at a current density of 50mAh g-1. USE - Method for improving stability of graphite or graphene cathode of potassium ion battery (claimed), used in large scale energy storage system. ADVANTAGE - The graphite cathode shows excellent electrochemical performance and structure stability. The potassium ion battery provides excellent cycle stability and electrochemical stability. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a potassium ion battery.