• 专利标题:   Graphene oxide/ZIF-8 composite diaphragm comprises thermally crosslinked polyvinyl alcohol/polyacrylic acid nanofiber film as base film, and negatively charged graphene oxide/positively charged ZIF-8 modified layer.
  • 专利号:   CN114335901-A
  • 发明人:   XU S, ZHU X
  • 专利权人:   BAOWU CARBON MATERIAL TECHNOLOGY CO LTD
  • 国际专利分类:   B82Y030/00, H01M050/403, H01M050/414, H01M050/431, H01M050/44, H01M050/454
  • 专利详细信息:   CN114335901-A 12 Apr 2022 H01M-050/454 202254 Chinese
  • 申请详细信息:   CN114335901-A CN11072644 09 Oct 2020
  • 优先权号:   CN11072644

▎ 摘  要

NOVELTY - A graphene oxide/ZIF-8 composite diaphragm comprises base film and multiple layers of graphene oxide/ZIF-8 modified layers arranged on base film. The base film is a thermally crosslinked polyvinyl alcohol/polyacrylic acid nanofiber film. The graphene oxide/ZIF-8 modified layer includes positively charged ZIF-8 layer and negatively charged graphene oxide layer that are self-assembled layer by layer on the base film driven by electrostatic adsorption force. USE - Graphene oxide/ZIF-8 composite diaphragm ADVANTAGE - The oxidation graphene/ZIF-8 composite diaphragm has good mechanical performance, chemical stability, and can effectively inhibit the shuttle effect of the polysulfide compound, so as to improve the electrochemical performance and service life of the lithium sulfur battery. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a preparation of the graphene oxide/ZIF 8 composite diaphragm comprising preparing thermally crosslinked polyvinyl alcohol/polyacrylic acid nanofiber film through electrospinning and thermal crosslinking treatment, using the thermally crosslinked polyvinyl alcohol/polyacrylic acid nanofiber film as base film, and sequentially assembling with positively charged ZIF-8 nanoparticles and negatively charged graphene oxide by electrostatic adsorption.