• 专利标题:   Catalyst used for selective hydrogenation reaction of hydrocarbon comprises graphene carrier and metal active component consisting of at least one of platinum, palladium, copper and nickel.
  • 专利号:   CN102441374-A
  • 发明人:   TANG A, TANGBO H, XIE L, XU F, XU J, YANG Z, ZHAO J
  • 专利权人:   SHANGHAI XINNIAN PETROCHEMICAL ADDITIVES CO LTD
  • 国际专利分类:   B01J023/42, B01J023/44, B01J023/72, B01J023/755, B01J023/89, C10G045/36, C10G045/40
  • 专利详细信息:   CN102441374-A 09 May 2012 B01J-023/44 201250 Pages: 9 Chinese
  • 申请详细信息:   CN102441374-A CN10504887 12 Oct 2010
  • 优先权号:   CN10504887

▎ 摘  要

NOVELTY - A selective hydrogenation catalyst (I) comprises graphene carrier and metal active component consisting of platinum, palladium, copper and/or nickel. USE - Catalyst (I) used for selective hydrogenation reaction (claimed) of hydrocarbon, such as cracked gasoline selective hydrogenation reaction and 2-4C selective hydrogenation reaction. ADVANTAGE - The catalyst (I) is relatively high in catalytic hydrogenation activity, good in diene hydrogenation selectivity, and good for prolonging the catalyst regeneration period. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: (1) preparation of selective hydrogenation catalyst (I), comprising (a) washing graphene with 10 mass % of nitric acid for 1-4 hours, washing with water until it becomes neutral, soaking in 2 wt.% of diluted ammonia water for 1 hour, drying at 120 degrees C for 3-6 hours to obtain graphene carrier; and (b) preparing the active metal into a precursor solution, soaking the graphene carrier in the precursor solution or spraying the precursor solution on the graphene carrier to obtain a graphene-supported catalyst precursor, drying, and subjecting into reduction treatment to obtain the catalyst (I); and (2) application of the catalyst (I) in selective hydrogenation reaction employing a reaction temperature of 35-180 degrees C, a hydrogen partial pressure of 1-6 MPa, a liquid hourly volume space velocity of 6-10/hour, and a hydrogen-to-oil volume ratio of 40-400.