• 专利标题:   Catalyst used for synthesizing copper based methanol oxidation product, comprises copper, zinc oxide, alumina and graphene oxide.
  • 专利号:   CN105772000-A
  • 发明人:   REN H, WANG X, XU S, LIU Z
  • 专利权人:   LANZHOU CHEM PHYSICS INST CHINESE ACAD
  • 国际专利分类:   B01J023/80, C07C029/154, C07C031/04
  • 专利详细信息:   CN105772000-A 20 Jul 2016 B01J-023/80 201664 Pages: 7 Chinese
  • 申请详细信息:   CN105772000-A CN10774261 16 Dec 2014
  • 优先权号:   CN10774261

▎ 摘  要

NOVELTY - Catalyst comprises 45-65 wt.% copper, 25-45 wt.% zinc oxide, 5-10 wt.% alumina and 5-15 wt.% graphene oxide. USE - Catalyst used for synthesizing copper based methanol oxidation product. ADVANTAGE - The catalyst has high activity, high stability, high carbon dioxide conversion rate, and ensures high yield of copper based methanol oxidation product. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing catalyst, which involves: (A) dispersing graphene oxide in deionized water to obtain graphite oxide solution; (B) adding graphite oxide solution to copper(ii) nitrate trihydrate, zinc nitrate hexahydrate and aluminum nitrate nonahydrate mixed nitrate solution; (C) adding mixed nitrate solution to mixed solution of nitric acid solution; (D) adding mixed nitric acid solution to mixed solution of nitric oxide; (E) mixing mixed nitrate solution and graphene oxide at 343-353 Kelvin; (F) adding sodium carbonate solution to mixed solution and stirring to maintain pH value at 6-8; (G) stirring continuously for 4-5 hours and mixing mixed solution with the graphene oxide; (H) stirring continuously for 10 hours; (I) pouring mixture into vacuum filtration device; (J) washing product with deionized water; and (K) drying product at 348-368 Kelvin and calcining at 613-633 Kelvin for 4-6 hours under argon atmosphere to obtain catalyst.