• 专利标题:   Flaky amorphous silicon-carbon-oxygen aerogel comprises amorphous silicon-carbon-oxygen ceramic coated on surface of amorphous flaky shape graphene oxide and forming sandwich structure, where graphene oxide is in flaky shape of template.
  • 专利号:   CN114621011-A
  • 发明人:   ZHANG L, ZHAO K, WANG J, YE F, CHENG L
  • 专利权人:   UNIV NORTHWESTERN POLYTECHNICAL
  • 国际专利分类:   B01J013/00, C04B035/56, C04B035/622, C09K003/00
  • 专利详细信息:   CN114621011-A 14 Jun 2022 C04B-035/56 202279 Chinese
  • 申请详细信息:   CN114621011-A CN10240001 12 Mar 2022
  • 优先权号:   CN10240001

▎ 摘  要

NOVELTY - A flaky amorphous silicon-carbon-oxygen aerogel comprises amorphous silicon-carbon-oxygen ceramic coated on the surface of graphene oxide and forming a sandwich structure. The graphene oxide is in a flaky shape of the template and in an amorphous state. USE - Flaky amorphous silicon-carbon-oxygen aerogel. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the preparation of flaky amorphous silicon-carbon-oxygen aerogel, which involves (s1) preparing a graphene oxide aerogel template by adopting freeze-drying method, (s2) mixing polycarbosilane and xylene to obtain a precursor solution, and (s3) preparing silicon-carbon-oxygen aerogel by combining a template method with a precursor impregnation cracking method, placing a precursor solution on the lower layer of a crucible, and graphene oxide aerogel template on the upper layer of the crucible, and (s4) putting the crucible into a tube furnace, heating at 100 ℃ at the rate of 5 ℃/minute and preserving heat for 3 hours under the protection of argon atmosphere with the gas flow of 0.2 L/minute, heating at 220 ℃ and preserving heat for 2 hours, and heating at 900℃ and preserving heat for 2 hours to perform a polymer cracking reaction. The mass ratio of polycarbosilane and xylene is 1:5-10, and the precursor solution to graphene oxide aerogel is 100-500:1.