• 专利标题:   Preparation of zinc oxide/graphene/graphene oxide/carbon nanotube aerogel, involves mixing graphene oxide aqueous solution, carbon nanotube aqueous solution and zinc salt solution, stirring to obtain precursor sol, filtering to obtain wet gel, putting wet gel into dryer to obtain composite aerogel.
  • 专利号:   CN113578212-A, CN113578212-B
  • 发明人:   WANG J, XU C, GUO J, YUAN P, ZHANG T, DU W, ZHAO S, CHENG F, LI E, MA D, GONG S, SHEN Y
  • 专利权人:   UNIV XIAN TECHNOLOGY
  • 国际专利分类:   B01J013/00, B01J021/18, B01J023/06, B01J032/00, C01B032/19, C01G009/02, C02F001/28, C02F001/30, C02F101/30, C02F101/34, C02F101/36, C02F101/38
  • 专利详细信息:   CN113578212-A 02 Nov 2021 B01J-013/00 202234 Chinese
  • 申请详细信息:   CN113578212-A CN10780172 09 Jul 2021
  • 优先权号:   CN10780172

▎ 摘  要

NOVELTY - A preparation of zinc oxide/graphene/graphene oxide/carbon nanotube aerogel, involves (1) mixing the graphene oxide aqueous solution, the carbon nanotube aqueous solution and the zinc salt solution uniformly, adding the alkaline solution dropwise to the above mixed solution in four times, stirring constantly to make the alkali and the mixed solution fully react to obtain the precursor sol, (2) vacuum filtering the precursor sol obtained in Step (1) to obtain a wet gel, (3) putting the wet gel obtained in step (2) into a freeze dryer for rapid freezing and freeze drying to obtain a zinc hydroxide/graphene oxide/carbon nanotube composite aerogel, (4) putting the zinc hydroxide/graphene oxide/carbon nanotube composite aerogel obtained in step (3) into a thermostat or a tube furnace for heat treatment to decompose the zinc hydroxide into zinc oxide, partially reducing the graphene oxide to graphene. USE - Preparation of zinc oxide/graphene/graphene oxide/carbon nanotube aerogel (claimed) used in photocatalytic material for degrading organic dyes. ADVANTAGE - The aerogel improves the degradation efficiency and degradation rate of the photocatalytic material to degrade organic dyes. DETAILED DESCRIPTION - A preparation of zinc oxide/graphene/graphene oxide/carbon nanotube aerogel, involves (1) mixing the graphene oxide aqueous solution, the carbon nanotube aqueous solution and the zinc salt solution uniformly, adding the alkaline solution dropwise to the above mixed solution in four times, once every 1 minute, 5-10 ml each time, and maintaining the dropping acceleration rate of 5-10 drops per second, stirring constantly to make the alkali and the mixed solution fully react to obtain the precursor sol, (2) vacuum filtering the precursor sol obtained in Step (1) to obtain a wet gel, (3) putting the wet gel obtained in step (2) into a freeze dryer for rapid freezing and freeze drying to obtain a zinc hydroxide/graphene oxide/carbon nanotube composite aerogel, (4) putting the zinc hydroxide/graphene oxide/carbon nanotube composite aerogel obtained in step (3) into a thermostat or a tube furnace for heat treatment for 0.5-4.0 hours to decompose the zinc hydroxide into zinc oxide, partially reducing the graphene oxide to graphene.