• 专利标题:   Surface modified silica/graphene oxide nano-composite material, prepared by binding amino group to silica nanoparticles and binding carboxy and epoxy functional group on both sides of two-dimensional graphene oxide nano-sheets.
  • 专利号:   CN105399987-A
  • 发明人:   CHEN L, FU J, SHI L, YU W, YIN J, ZONG P, SHANG D
  • 专利权人:   UNIV SHANGHAI
  • 国际专利分类:   C08K003/04, C08K009/02, C08L101/00, C09C001/46, C09C003/06
  • 专利详细信息:   CN105399987-A 16 Mar 2016 C08K-009/02 201640 Pages: 7 English
  • 申请详细信息:   CN105399987-A CN10613372 24 Sep 2015
  • 优先权号:   CN10613372

▎ 摘  要

NOVELTY - Surface modified silica/graphene oxide nano-composite material, is claimed. The nano-composite material is prepared by binding amino group to silica nanoparticles and binding carboxy and epoxy functional group on both sides of two-dimensional graphene oxide nano-sheets to form an amide bond, and to obtain a covalently bound silica/graphene oxide nano-composite. The mass ratio of graphene oxide and amino group-containing silica nanoparticle is 1:2-10. The amino group-containing silica nanoparticle is a core-shell structure of nuclear amino coated silicon dioxide. USE - Used as a surface modified silica/graphene oxide nano-composite material. ADVANTAGE - The method is short, economical and suitable for large scale industrial production. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing surface modified silica/graphene oxide nano-composite material, comprising dissolving the amino group-containing silica sol and graphene oxide in N,N-dimethylformamide respectively, where the mass fraction of amino group-containing silica in silica sol is 2-10 times to the amount of dilute solution of graphene oxide, and the concentration of silica sol and graphene oxide is 0.1-2 mg/ml, drop-wisely adding the amino group-containing silica sol-N,N-dimethylformamide solution into graphene oxide-N,N-dimethylformamide solution at a rate of 1-3 drops/second, stirring for 1 hour, ultrasonicating for 20-30 minutes, raising temperature for 10-12 hours, reacting for 2 hours by bouncing back for every 10 minutes, repeatedly washing with N,N-dimethylformamide ultrasonically, then filtering.