• 专利标题:   Preparing graphene or poly(3,4-ethylenedioxythiophene) composite nanomaterial comprises e.g. adding water into graphene oxide, adding 3,4-ethylenedioxythiophene monomer, and transferring obtained mixed solution into reacting kettle.
  • 专利号:   CN102585174-A, CN102585174-B
  • 发明人:   SUN D, ZHANG J
  • 专利权人:   UNIV NANJING
  • 国际专利分类:   C01B031/04, C08G061/12, C08K003/04
  • 专利详细信息:   CN102585174-A 18 Jul 2012 C08G-061/12 201307 Pages: 9 Chinese
  • 申请详细信息:   CN102585174-A CN10003540 09 Jan 2012
  • 优先权号:   CN10003540

▎ 摘  要

NOVELTY - Preparing graphene/poly(3,4-ethylenedioxythiophene) composite nanomaterial comprises: (a) adding water into graphene oxide, adding 3,4-ethylene dioxythiophene monomer, electrostatically adsorbing and conjugating the 3,4-ethylenedioxythiophene and graphene oxide; (b) dialyzing to remove redundant 3, 4-ethylenedioxythiophene monomer using water to obtain grapheme oxide/3, 4-ethylenedioxythiophene; and (c) transferring obtained mixed solution into reacting kettle, cooling reaction kettle, taking out reacted kettle sample, and filtering reacted kettle sample to obtain composite nanomaterial. USE - The method is useful for preparing graphene/poly(3,4-ethylenedioxythiophene) composite nanomaterial. ADVANTAGE - The method is capable of rapidly and conveniently preparing the graphene/poly(3,4-ethylenedioxythiophene) composite nanomaterial in an environmentally friendly manner. DETAILED DESCRIPTION - Preparing graphene/poly3,4-ethylenedioxythiophene composite nanomaterial comprises: (a) adding 100 ml of water solution into graphene oxide, where the graphene oxide has concentration of 0.1-5 mg/ml, adding 50-2500 ml of 3,4-ethylene dioxythiophene monomer into the mixed solution, mechanically stirring the mixed solution for 30 minutes to completely mix, electrostatically adsorbing and conjugating the 3,4-ethylenedioxythiophene and graphene oxide to obtain graphene oxide/3,4-ethylenedioxythiophene compound; (b) dialyzing the graphene compound to remove the redundant 3,4-ethylenedioxythiophene monomer using distilled water to obtain graphene oxide/3,4-ethylenedioxythiophene compound, and adsorbing 3,4-ethylenedioxythiophene monomer with surface saturation; and (c) transferring graphene oxide/3, 4 ethylenedioxythiophene solution into a microwave hydrothermal reacting kettle i.e. quartz reacting kettle for 10-20 minutes, where the microwave hydrothermal reaction kettle temperature is 140-160 degrees C, the microwave reacting kettle power is 200 watts and the reaction kettle pressure is 180 pounds/square inch, naturally cooling the microwave reaction kettle to room temperature, taking out the reacted kettle sample, and filtering the reacted kettle sample to obtain graphene/poly (3,4-ethylenedioxythiophene) compound nanomaterial.