• 专利标题:   Chemically-modified oxidized graphene ionic-type sewage treatment agent for treating heavy metal ion-containing wastewater, is prepared by carrying out chemical reaction of oxidized graphene with organic phosphoric acid and organosiloxane.
  • 专利号:   CN106167285-A
  • 发明人:   XIE Y, XU J, KANG L, YAO D
  • 专利权人:   UNION FOSHAN CHEM CO LTD, SHAOGUAN HEZHONG CHEM CO LTD
  • 国际专利分类:   B01J020/22, C02F001/28, C02F001/62, C07F009/564
  • 专利详细信息:   CN106167285-A 30 Nov 2016 C02F-001/28 201717 Pages: 6 Chinese
  • 申请详细信息:   CN106167285-A CN10591106 25 Jul 2016
  • 优先权号:   CN10591106

▎ 摘  要

NOVELTY - A chemically-modified oxidized graphene ionic-type sewage treatment agent (I) is prepared by oxidizing graphene, and carrying out chemical reaction of the oxidized graphene with an organic phosphoric acid and an organosiloxane. USE - Chemically-modified oxidized graphene ionic-type sewage treatment agent used for treating industrial wastewater containing heavy metal ions e.g. divalent lead and hexavalent chromium. ADVANTAGE - The chemically-modified oxidized graphene ionic-type sewage treatment agent is effective, and has excellent adsorption selectivity with respect to heavy metal ions. DETAILED DESCRIPTION - A chemically-modified oxidized graphene ionic-type sewage treatment agent is prepared by oxidizing graphene, and carrying out chemical reaction of the oxidized graphene with an organic phosphoric acid and an organosiloxane. The chemically modified oxidized graphene ion-type sewage treatment agent is of formula (I). An INDEPENDENT CLAIM is included for preparation of chemically-modified oxidized graphene ionic-type sewage treatment agent, which involves washing graphene oxide with 0.05-0.10 mol/L hydrochloric acid solution and deionized water, filtering, vacuum-drying to obtain a oxidized graphene, adding 5 pts. wt. nitrogen-containing organic phosphoric acid compound to a solution of methanol or ethanol, adding 4-5 pts. wt. organosiloxane, stirring at 25-35 degrees C for 2 hours to obtain a solution, adding 50-100 pts. wt. oxidized graphene to the solution, stirring at 25-35 degrees C for 24 hours, filtering, washing with methanol or ethanol and water, and vacuum-drying at 40-50 degrees C for 24 hours.