• 专利标题:   Polypropylene composite material comprises polypropylene, modified graphene comprising amino and/or azide groups and rare earth composite.
  • 专利号:   CN112724531-A
  • 发明人:   MA B, HU M, LU J, CAI Q
  • 专利权人:   JIANGMEN GUANGRUI NEW MATERIAL TECHNOLOGY CO LTD
  • 国际专利分类:   C08K003/04, C08K005/00, C08K009/04, C08L023/12, C08L023/14, C09K005/14
  • 专利详细信息:   CN112724531-A 30 Apr 2021 C08L-023/12 202150 Pages: 12 Chinese
  • 申请详细信息:   CN112724531-A CN11626576 30 Dec 2020
  • 优先权号:   CN11626576

▎ 摘  要

NOVELTY - Polypropylene composite material comprises 100 pts. wt. polypropylene, 1-10 pts. wt. modified graphene comprising amino and/or azide groups and 1-20 pts. wt. rare earth composite, where the content of the amino group and/or azide group is 0.1-5%, and the coordination number of the rare earth composite is 3-8. USE - Polypropylene composite material. ADVANTAGE - The composite material has excellent thermal conductivity. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing the composite material, involving (a) dispersing rare earth oxides and 4-p-aminobenzoic acid in water at a stirring speed of 1000-3000 rpm, and heating at 40-60 degrees C to fully carry out the coordination reaction, (b) centrifuging the above solution, drying at 90-120 degrees C for 14-30 hours, adding siloxane coupling agent, and stirring at 500-800 rpm for 10-20 minutes to obtain the rare earth composite, and (c) amidating 4-p-aminobenzoic acid and/or azide graphene to obtain modified graphene, adding the rare earth composite and modified graphene to the polypropylene resin, evenly mixing using a high-speed mixer, passing the uniformly mixed materials through an extruder for granulation, where the feeding section is 180-210 degrees C, and the plasticizing extrusion section is 180-210 degrees C, and the melt conveying section has an extrusion temperature of 200-230 degrees C, and the head temperature is 200-220 degrees C, and the vacuum degree is 0.3-0.8 MPa.