• 专利标题:   Sulfur-doped carbon-coated nickel nanomaterial used for manufacturing lithium-sulfur battery positive electrode active material, comprises sulfur-doped carbon-coated nickel nanoparticles containing metallic nickel cores and sulfur-doped graphitized carbon layer shell.
  • 专利号:   CN115394970-A
  • 发明人:   LI H, ZONG M, XIE J, WU G, RONG J, YANG Y
  • 专利权人:   CHINA PETROLEUM CHEM CORP RES INST, CHINA PETROLEUM CHEM CORP
  • 国际专利分类:   B82Y030/00, H01M010/052, H01M004/36, H01M004/38, H01M004/62
  • 专利详细信息:   CN115394970-A 25 Nov 2022 H01M-004/36 202315 Chinese
  • 申请详细信息:   CN115394970-A CN10571743 25 May 2021
  • 优先权号:   CN10571743

▎ 摘  要

NOVELTY - Sulfur-doped carbon-coated nickel nanomaterial comprises sulfur-doped carbon-coated nickel nanoparticles, and the sulfur-doped carbon-coated nickel nanoparticles contain metallic nickel cores and a sulfur-doped graphitized carbon layer shell coated on the surface of the metallic nickel core. The pore size of the sulfur-doped carbon-coated nickel nanomaterial has a mesoporous peak. USE - Sulfur-doped carbon-coated nickel nanomaterial. ADVANTAGE - The sulfur-doped carbon-coated nickel nanomaterial significantly improves the low-rate charge-discharge performance and specific capacity of the lithium-sulfur battery. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for the following: (1) a method for preparing sulfur-doped carbon-coated nickel nanomaterial, which involves forming a homogeneous solution with a nickel source, a polyvalent organic carboxylic acid, and a solvent, removing the solvent in the homogeneous solution to obtain a precursor, mixing and grinding the precursor with a solid sulfur source to form a mixture, and then subjecting the mixture to high-temperature pyrolysis under an inert atmosphere or a reducing atmosphere; (2) a lithium-sulfur battery positive electrode active material based on sulfur-doped carbon-coated nickel nanomaterials, where the positive electrode active material is a composite material containing sulfur-doped carbon-coated nickel nanomaterials, graphene, and elemental sulfur; and (3) a method for preparing lithium-sulfur battery cathode active material based on sulfur-doped carbon-coated nickel nanomaterials, which comprises mixing sulfur-doped carbon-coated nickel nanomaterials, graphene, and elemental sulfur to obtain a mixture, and subjecting the mixture to high temperature treatment at a temperature not lower than the melting temperature of sulfur under an inert atmosphere.