• 专利标题:   Anode material used in sodium ion battery, comprises manganese-based phosphate anode material containing vanadium and titanium.
  • 专利号:   CN113929069-A
  • 发明人:   LIU H, XU C, ZHAO J
  • 专利权人:   INST PROCESS ENG CHINESE ACAD SCI
  • 国际专利分类:   C01B025/45, C01B032/05, H01M010/054, H01M004/58, H01M004/62
  • 专利详细信息:   CN113929069-A 14 Jan 2022 C01B-025/45 202228 Chinese
  • 申请详细信息:   CN113929069-A CN11170822 08 Oct 2021
  • 优先权号:   CN11170822

▎ 摘  要

NOVELTY - Anode material is a manganese-based on phosphate anode material containing vanadium and titanium, and has sodium-titanium-vanadium-manganese-phosphate complex of formula of: Na3+delta+(4-n)x+2yTi1-delta-x-yMn+xVdeltaMn1+y(PO4)3 (I), is new. USE - The anode material is used for sodium ion battery (claimed) e.g. secondary rechargeable lithium ion battery used as energy storage device. ADVANTAGE - The anode material can obtain higher effective specific capacity, inhibits manganese-rich phosphate anode voltage hysteresis phenomenon, and exhibits high dynamic performance and multiplying power performance. The electrochemical performance of the material is improved. DETAILED DESCRIPTION - Anode material is a manganese-based on phosphate anode material containing vanadium and titanium, and has sodium-titanium-vanadium-manganese-phosphate complex of formula of: Na3+delta+(4-n)x+2yTi1-delta-x-yMn+xVdeltaMn1+y(PO4)3 (I), is new. An INDEPENDENT CLAIM is included for a a preparation method of the anode material, involving mixing the raw material of the anode material with a solvent to obtain a precursor, drying the precursor and then sintering to obtain the anode material. Mn+ = Li+, K+, Mg2+, Ca2+, Sr2+, Zn2+, Co2+, Ni2+, Cu2+, Al3+, Cr3+, Fe3+, Y3+, La3+, Ga3+, Zr4+, Sn4+, Nb5+ or W6+; x and y = 0-0.5; delta = 0-0.5; n = greater than or equal to1.