• 专利标题:   Method for modifying carbon fiber surface, involves dissolving graphene oxide in water followed by obtaining graphene oxide water solution, and carrying out thermal treatment with coated carbon fiber in furnace to obtain finished product.
  • 专利号:   CN103243544-A, CN103243544-B
  • 发明人:   HUANG S, LV C, WU G
  • 专利权人:   CHINESE ACAD SCI SHANXI INST COAL CHEM
  • 国际专利分类:   C25D011/02, D06M010/06
  • 专利详细信息:   CN103243544-A 14 Aug 2013 D06M-010/06 201401 Pages: 10 Chinese
  • 申请详细信息:   CN103243544-A CN10163863 07 May 2013
  • 优先权号:   CN10163863

▎ 摘  要

NOVELTY - A carbon fiber surface modification method involves dissolving graphene oxide in water, and adjusting pH value of an aqueous solution to 8.0-13.0. The resulted solution is stirred and dispersed by an ultrasonic wave to obtain a graphene oxide water solution. The solution is stewed into an electrolytic cell and a conductive metal or a graphite material as a cathode material. Voltage or current is applied to the carbon fiber electrode, and the carbon fiber is coated with graphene oxide. A thermal treatment is carried out with the coated carbon fiber in a furnace to obtain a finished product. USE - Method for modifying a carbon fiber surface. ADVANTAGE - The method enables modifying the carbon fiber surface in a simple, cost-effective and environment-friendly manner. DETAILED DESCRIPTION - A carbon fiber surface modification method involves dissolving 0.01-2 g/l graphene oxide in water, and adjusting pH value of an aqueous solution to 8.0-13.0 by using alkali. The resulted solution is stirred at 20-300 rpm for 60 hours, and the stirred solution is dispersed by 30-300 watt ultrasonic wave for 10 minutes-10 hours to obtain a graphene oxide water solution. The water solution is stewed into an electrolytic cell at 20-80 degrees C followed by utilizing a carbon fiber as an anode material of an electrode, and a conductive metal or a graphite material as a cathode material. Voltage or current is applied to the carbon fiber electrode by a constant potential method or constant current method, and the carbon fiber is coated with graphene oxide. A thermal treatment is carried out with the coated carbon fiber in a furnace at 80-600 degrees C for 10 seconds-60 minutes to obtain a finished product, where furnace ambient medium is air, oxygen, ozone, nitrogen, argon or ammonia gas.