• 专利标题:   Carbon-supported iridium(IV) oxide-iridium heterojunction composite catalyst with strawberry-shaped structure useful for e.g. hydrogen evolution and oxygen evolution in electrolysis of water, and electrode electrocatalyst.
  • 专利号:   CN113398923-A
  • 发明人:   LIU J, MO S, JIN C, LI R, WANG F
  • 专利权人:   UNIV BEIJING CHEM TECHNOLOGY
  • 国际专利分类:   B01J023/46, C25B011/093, C25B001/04, H01M008/0612
  • 专利详细信息:   CN113398923-A 17 Sep 2021 B01J-023/46 202195 Pages: 10 Chinese
  • 申请详细信息:   CN113398923-A CN10562841 24 May 2021
  • 优先权号:   CN10562841

▎ 摘  要

NOVELTY - Carbon-supported iridium(IV) oxide-iridium heterojunction composite catalyst with strawberry-shaped structure, is claimed. The composite catalyst is black solid powder. The iridium(IV) oxide-iridium heterojunction is uniformly supported on the surface of the carbon support. The amorphous iridium(IV) oxide layer is epitaxially on the surface of the metal iridium. The thickness of the iridium(IV) oxide layer is less than 1 nanometer, and the ultra-thin iridium(IV) oxide layer is in a state of low chemical coordination and stress shrinkage. USE - The composite catalyst is useful for hydrogen evolution and oxygen evolution in electrolysis of water, preferably devices involving oxygen evolution reaction or hydrogen evolution reaction, e.g. electrolyzed water tank and integrated renewable fuel cell (claimed), electrode electrocatalyst for oxygen evolution and hydrogen evolution reaction in electrolysis tanks, rechargeable zinc-air batteries and other devices. ADVANTAGE - The catalyst has excellent electrocatalytic activity for water splitting. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the composite catalyst, comprising (1) using metal iridium salt as precursor, carbon material as carrier, and organic amine as stabilizer, dispersant and anchor of metal salt, and fully mixing iridium salt and carbon carrier through solution dispersion, and (2) reducing the metal iridium by carbothermal then under inert atmosphere and uniformly loading on the carbon support, where the stabilizer and dispersant inhibit the growth of the catalyst nanocrystals and regulates the composition and structure of the iridium-based catalyst, and preparing carbon-supported iridium(IV) oxide-iridium heterojunction composite catalyst with strawberry-shaped structure.