• 专利标题:   Graphene-supported thiadiazole complex containing furfural reactive group useful as rust inhibitor to protect seawater corrosive media.
  • 专利号:   CN107434805-A
  • 发明人:   TIAN H, LI W, HOU L, HOU B
  • 专利权人:   INST OCEANOLOGY CHINESE ACAD SCI
  • 国际专利分类:   C07D417/12, C23F011/16
  • 专利详细信息:   CN107434805-A 05 Dec 2017 C07D-417/12 201810 Pages: 9 Chinese
  • 申请详细信息:   CN107434805-A CN11151668 14 Dec 2016
  • 优先权号:   CN11151668

▎ 摘  要

NOVELTY - Graphene-supported thiadiazole complex containing furfural reactive group is claimed. The complex is obtained by chemical loading furaldehyde-(5-(p-methylphenyl)-1,3,4-thiadiazole-2-mercapto)-acetylhydrazone in molecular layer of graphene molecular oxygen functional groups active site. USE - The reactive group is useful as rust inhibitor to protect seawater corrosive media (claimed). ADVANTAGE - The reactive group has small dosage, high performance, sustained role ability, and inhibits corrosion of carbon steel damage. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) preparing graphene-supported thiadiazole complex containing furfural reactive group comprising (i) adding potassium permanganate and graphite sheet into concentrated sulfuric acid mixed system with graphite mass fraction of 35% in a mass ratio of 1:1.1 after sulfate-intercalation, permanganate-oxidation and activation to obtain monolayer graphene oxide aqueous suspension, (ii) adding furaldehyde-(5-(p-methylphenyl)-1,3,4-thiadiazole-2-mercapto)-acetylhydrazone into graphene oxide aqueous suspension, protonated grafting, then adding excessive glucose and reducing; and (2) use of graphene-supported thiadiazole complex containing furfural reactive group as rust inhibitor to protect seawater corrosive media.