• 专利标题:   Preparing germanium embedded graphene layer-based three-dimensional carbon network composite material useful in preparing lithium-ion battery cathode, comprises e.g. preparing pluronic F-127 solution, adding germanium(IV) oxide, graphene oxide and carbon nanotubes, sonicating, and carbonizing.
  • 专利号:   CN116081606-A
  • 发明人:   LIU Y, ZHENG X, GUO X, GU H, ZHANG J
  • 专利权人:   UNIV JIANGSU SCI TECHNOLOGY
  • 国际专利分类:   B22F001/054, B22F009/22, C01B032/168, C01B032/184, H01M004/36, H01M004/48, H01M004/587
  • 专利详细信息:   CN116081606-A 09 May 2023 C01B-032/184 202349 Chinese
  • 申请详细信息:   CN116081606-A CN10045206 30 Jan 2023
  • 优先权号:   CN10045206

▎ 摘  要

NOVELTY - Preparing germanium embedded graphene layer-based three-dimensional carbon network composite material, comprises (i) preparing 1-4 wt.% pluronic F-127 solution, then adding germanium(IV) oxide, and stirring at room temperature for 0.5-1.5 hours to obtain clear and transparent mixed solution, where the mass ratio between germanium(IV) oxide and pluronic F-127 is 1:4, and (ii) adding 10 mg graphene oxide into the mixed solution to obtain black germanium(IV) oxide/pluronic F-127/graphene oxide composite material, stirring vigorously for 0.5-1 hour, adding into 5-40 mg carbon nanotubes, sonicating for 1-1.5 hours, then stirring for 1.5-2.5 hours, uniformly dispersing carbon nanotubes, freeze-drying the sample, and removing the moisture in the sample to obtain a black precursor, where the mass ratio of between graphene oxide and germanium(IV) oxide is 1:10, and the mass ratio between carbon nanotubes and germanium dioxide is 1-8:20. USE - The three-dimensional carbon network composite material is useful in preparing lithium-ion battery cathode (claimed). ADVANTAGE - The method: is low cost, efficient, and environmentally-friendly. The composite material: has improved electrical conductivity, and improved electrochemical performance; promotes rapid ion transport; and fully exposes reactive active sites.