• 专利标题:   Producing modified graphene used in modified graphene-resin composite, modified graphene sheet, and modified graphene dispersion, involves bonding azide group to carbon atom of surface of graphene through radical addition reaction based on abstraction of hydrogen atom in an aqueous system.
  • 专利号:   US2023127728-A1
  • 发明人:   KOBAYASHI Y, SUZUKI K, KITAO A, WATANABE T
  • 专利权人:   CANON KK
  • 国际专利分类:   C07C015/08, C07C015/085, C07C205/06, C07C233/65, C07C233/78, C07C025/13, C07C255/50, C07C049/78, C07C063/16, C07F009/38, C08G077/42, C08K003/04, C08K009/06, C09C001/44, C09D005/24, C09D007/62
  • 专利详细信息:   US2023127728-A1 27 Apr 2023 C09C-001/44 202339 English
  • 申请详细信息:   US2023127728-A1 US051195 31 Oct 2022
  • 优先权号:   JP034911, JP034913, JP021921

▎ 摘  要

NOVELTY - Producing modified graphene involves bonding azide group to a carbon atom of a surface of graphene through a radical addition reaction based on an abstraction of a hydrogen atom from azide compound in an aqueous system. USE - Method for producing modified graphene used in modified graphene-resin composite, modified graphene sheet, and modified graphene dispersion. ADVANTAGE - The hydrogen atom can be more efficiently abstracted from the hydrazine compound, and hence the reaction efficiency can be improved by using oxidant having an oxidation potential of +0.50 V. DETAILED DESCRIPTION - Producing modified graphene involves bonding a group of formula HN=N-A1 to a carbon atom of a surface of graphene through a radical addition reaction based on an abstraction of a hydrogen atom from a compound HN=N-A1 in an aqueous system. A1=represents a group of formula -Ar1-X1-(Y1)n1; Ar1=6-18C arylene group; X1=a single bond, a linear, branched, or 1-20C cyclic alkylene group, and a group obtained by substituting carbon atom in a linear, branched or cyclic 1-20C alkylene group with structure selected from -O-, -NH-, -CO-, -COO-, -CONH-, an arylene group, or group of formula (I); Y1=an atom or group selected from H, F, Cl, Br, and I, 1-6C fluoroalkyl group, a cyano group, a nitro group, an acyl group, an amide group, a vinyl group, a carboxylic acid group, a carboxylic acid ester group, and a phosphoric acid group, 3-6C alkylsilyl group, 3-6C alkylsilyl ether group, and a siloxane group; and n1=represents an integer of 1 or more.