• 专利标题:   Preparation of epoxide grafted amine dispersant-modified graphene involves adding graphene oxide product to benign solvent, dispersing, adding grafted epoxide amine, refluxing, centrifuging, freeze-drying and removing solvent.
  • 专利号:   CN107619044-A
  • 发明人:   ZHAO J, CHEN D, LIU H, YUAN J, LI F, SHEN W
  • 专利权人:   UNIV SHANDONG TECHNOLOGY
  • 国际专利分类:   C01B032/192, C08G065/26
  • 专利详细信息:   CN107619044-A 23 Jan 2018 C01B-032/192 201817 Pages: 15 Chinese
  • 申请详细信息:   CN107619044-A CN10914550 30 Sep 2017
  • 优先权号:   CN10914550

▎ 摘  要

NOVELTY - Preparation of epoxide grafted amine dispersant-modified graphene involves preparing graphite oxide by modified Hummers method, adding preset amount of graphene oxide product to benign solvent, ultrasonically dispersing, adding grafted epoxide amine, refluxing at preset temperature for preset time, washing using anhydrous ethanol and deionized water until neutral, separating by centrifugation, freeze-drying or heating-evaporating, and removing solvent. USE - Preparation of epoxide grafted amine dispersant-modified graphene (claimed). ADVANTAGE - The method efficiently and economically provides epoxide grafted amine dispersant-modified graphene by simple method without formation of agglomeration or deposition. DETAILED DESCRIPTION - Preparation of epoxide grafted amine dispersant-modified graphene involves adding preset amount of solvent to a reaction kettle, adding amino compound of formula: HO-R-NH2 (I) and catalyst, stirring, adding a solution of epoxy compound of formula (II) or epoxy compound (II), stirring at preset temperature and pressure, cooling to room temperature, obtaining grafted epoxide amine of formula: H2N-R-O-(CH2-CH(-R')-O)n-CH2-CH(-OH)-R' (III), preparing graphite oxide by modified Hummers method, adding preset amount of graphene oxide product to benign solvent, ultrasonically dispersing, adding grafted epoxide amine, refluxing at preset temperature for preset time, washing using anhydrous ethanol and deionized water until neutral, separating by centrifugation, freeze-drying or heating-evaporating, and removing solvent. R,R'=1-20C alkyl, aryl or ester group, double bond, alkoxysilyl or halo functional group;and n=1-10.