• 专利标题:   Preparation of discontinuous fiber-reinforced polyhexahydrotriazine resin-based thermally-conductive composite material involves prepolymerizing formaldehyde and aromatic amine, mixing with discontinuous fibers to obtain prepreg, and curing.
  • 专利号:   CN112694630-A, CN112694630-B
  • 发明人:   YUAN Y, MA Y, ZHAO J, LIU S
  • 专利权人:   UNIV SOUTH CHINA TECHNOLOGY
  • 国际专利分类:   C08G012/08, C08J005/24, C08K003/04, C08K003/08, C08K003/34, C08K003/38, C08K007/06, C08L061/22, C08L077/10, C08L079/04
  • 专利详细信息:   CN112694630-A 23 Apr 2021 C08J-005/24 202147 Pages: 16 Chinese
  • 申请详细信息:   CN112694630-A CN11527110 22 Dec 2020
  • 优先权号:   CN11527110

▎ 摘  要

NOVELTY - Preparation of discontinuous fiber-reinforced polyhexahydrotriazine resin-based thermally-conductive composite material involves uniformly dissolving formaldehyde and an aromatic amine in a water/aprotic solvent mixed solution, stirring and reacting the resulting reaction solution at 30-100 degrees C for 5-120 minutes for prepolymerization to obtain a prepolymer solution, uniformly mixing a thermally-conductive filler and discontinuous with the prepolymer solution, adding a solvent for precipitation, filtering the precipitate, and drying to obtain a prepreg (A), or prepolymerizing a formaldehyde and an aromatic amine in a water/aprotic solvent mixed solution, adding a solvent for precipitation, drying the precipitate to obtain a prepolymer powder, uniformly mixing with the thermally-conductive filler and discontinuous fibers to obtain a prepreg (B), and curing prepreg (A) or (B) by heat and pressure. USE - Preparation of discontinuous fiber-reinforced polyhexahydrotriazine resin-based thermally-conductive composite material. ADVANTAGE - The method produces discontinuous fiber-reinforced polyhexahydrotriazine resin-based thermally-conductive composite material having excellent mechanical property and thermal-conductive property, by simple process. The composite material can be efficiently recycled and reused. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for recycle of the composite material, which involves soaking the composite material in 5-30 ml/g strong acid/aprotic solvent mixed solution at 20-95 degrees C for 0.5-24 hours, filtering fibers from the degraded acid solution through a screen, washing with water, alkali solution, and water, and drying to recover the fibers, filtering and degrading the acid solution using a quantitative filter paper, washing with water, alkali solution, and water, and drying to recover the thermally-conductive filler, neutralizing the degraded acid solution, precipitating, filtering, washing with water, and drying through an alkaline solution to obtain the aromatic amine.