• 专利标题:   Preparation of graphene conductive foam by immersing and dispersing foam into water with graphene oxide, coating graphene oxide on surface of foam by padding process, and immersing into aqueous solution containing reducing agent.
  • 专利号:   CN102557022-A, CN102557022-B
  • 发明人:   LV Y, ZHAO S
  • 专利权人:   UNIV HANGZHOU DIANZI
  • 国际专利分类:   C01B031/04
  • 专利详细信息:   CN102557022-A 11 Jul 2012 C01B-031/04 201322 Pages: 6 Chinese
  • 申请详细信息:   CN102557022-A CN10052928 02 Mar 2012
  • 优先权号:   CN10052928

▎ 摘  要

NOVELTY - Preparation of graphene conductive foam includes obtaining graphene oxide; immersing and dispersing the foam into water with graphene oxide; coating the graphene oxide on the surface of the foam by padding process; immersing into aqueous solution containing reducing agent and conducting reduction reaction; and obtaining conductive foam having surface coated with graphene conductive layer. USE - Preparation of graphene conductive foam (claimed). ADVANTAGE - The graphene conductive foam has low density, high conductivity, large specific surface area, and low cost. DETAILED DESCRIPTION - Preparation of graphene conductive foam comprises: (A) adding sodium nitrate into concentrated sulfuric acid as reaction liquid, where content of sodium nitrate is 1-2 mass%; and adding graphite sheet into the reaction liquid at 1:80-100 mass ratio; (B) adding potassium permanganate into the reaction liquid; heating at 35-40 degrees C; and heat preserving for 60-90 minutes, where mass ratio of potassium permanganate and graphite sheet is 6-10:1; (C) adding water while magnetically stirring; heating at 85-95 degrees C; and heat preserving for 60-90 minutes, where mass ratio of water and graphite sheet is 350-400:1; (D) adding hydrogen peroxide (30 mass%); stirring for 5-10 minutes; and filtering, where mass ratio of hydrogen peroxide and graphite sheet is 5-6:1; (E) dispersing the filtrate with water; and centrifugally separating by centrifugal machine at 1000-2000 revolutions/minute (rpm); (F) dispersing the product produced by the first centrifugal separation with water; and performing second centrifugal separation by centrifugal machine at 8000-10000 rpm; (G) adding water into the product produced by second centrifugal separation; ultrasonically separating; and obtaining graphene oxide; (H) immersing and dispersing the foam into water with graphene oxide; and coating the graphene oxide on the surface of the foam by padding process, where mass ratio of foam and graphite sheet is 1-20:1; and (I) immersing into aqueous solution containing reducing agent and conducting reduction reaction; and obtaining conductive foam having surface coated with graphene conductive layer, where mass ratio of reducing agent in the aqueous solution and graphite sheet is 2-10:1.