• 专利标题:   Preparation of metal organic framework-supported three-dimensional ruthenium/graphene aerogel composite material by dissolving ruthenium trichloride and graphene oxide in ethylene glycol, reacting, ultrasonically treating and freeze drying.
  • 专利号:   CN107913674-A, US2019126236-A1
  • 发明人:   LU J, CHEN D, JIANG J
  • 专利权人:   UNIV SOOCHOW, UNIV SOOCHOW
  • 国际专利分类:   B01D053/02, B01D053/62, B01D053/86, B01J020/22, B01J020/28, B01J020/30, B01J031/22, B01J020/20
  • 专利详细信息:   CN107913674-A 17 Apr 2018 B01J-020/22 201831 Pages: 11 Chinese
  • 申请详细信息:   CN107913674-A CN11053331 27 Oct 2017
  • 优先权号:   CN11053331

▎ 摘  要

NOVELTY - Preparation of metal organic framework (MOF)-supported three-dimensional (3D) ruthenium/graphene aerogel composite material comprises (A) dissolving ruthenium trichloride and graphene oxide in ethylene glycol, reacting, ultrasonically treating, and freeze drying to obtain 3D ruthenium/graphene aerogel; (B) subjecting the 3D ruthenium/graphene aerogel surface to carboxylation reaction to obtain carboxy-rich 3D ruthenium/graphene aerogel composite material; and (C) surface modifying the carboxy-rich 3D ruthenium/graphene aerogel composite material, and obtaining the product. USE - Preparation of MOF-supported 3D ruthenium/graphene aerogel composite material used for continuous processing of carbon monoxide (CO) or in preparation of CO continuous processing agent (all claimed). ADVANTAGE - The method has relatively simple operation, provides MOF-supported 3D ruthenium/graphene aerogel composite material, which has adsorption performance of MOF material and catalytic performance of catalyst, thus, forming a cycle of adsorption and catalytic processing of CO, and excellent processing performance, increases reaction rate of CO, and is very suitable for industrial application. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: (1) 3D ruthenium/graphene aerogel comprising step (A) per se; and (2) preparation of carboxy-rich 3D ruthenium/graphene aerogel composite material comprising step (B) per se.