• 专利标题:   Manufacture of graphene oxide-polymer nanocomposite for preparing fuel barrier material, involves thermally-reducing graphene oxide, and polymerizing monomer when obtained thermally-reduced graphene oxide having preset amount of oxygen.
  • 专利号:   EP2960274-A1
  • 发明人:   BOBENRIETH A
  • 专利权人:   SOLVAY SA
  • 国际专利分类:   C01B031/02, C01B031/04, C08F002/44, C08K003/00, C08K003/04, C08L077/06, C08L077/10
  • 专利详细信息:   EP2960274-A1 30 Dec 2015 C08K-003/00 201607 Pages: 26 English
  • 申请详细信息:   EP2960274-A1 EP173534 23 Jun 2014
  • 优先权号:   EP173534

▎ 摘  要

NOVELTY - Manufacture of a thermally-reduced graphene oxide-polymer nanocomposite from graphene oxide and monomer(s) involves thermally-reducing graphene oxide to form thermally-reduced graphene oxide, and polymerizing monomer(s) in the presence of thermally-reduced graphene oxide to obtain nanocomposite. The monomers are polymerized when the oxygen content of the thermally-reduced graphene oxide is less than 15 wt.%. The thermal-reduction process and polymerization process are performed in the same reactor. USE - Manufacture of thermally-reduced graphene oxide-polymer nanocomposite for masterbatch (all claimed) used for preparing fuel barrier material for automotive application such as fuel tanks and pipes. ADVANTAGE - The method enables economical manufacture of thermally-reduced graphene oxide having improved mechanical, barrier and electrical properties. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) graphene material-polymer nanocomposite, which comprises less than 3 wt.% (preferably less than 2 wt.%) graphene material, and has a transversal resistivity of less than 105 with respect to reference nanocomposite obtained by in situ reduction of the graphene oxide and the polymerization of the polymer in presence of the graphene oxide; and (2) masterbatch, which comprises 3 wt.% (preferably 5-10 wt.%) thermally-reduced graphene oxide with respect to the total weight of the masterbatch.