• 专利标题:   New pyrane functional group based ring-opening metathesis polymerization initiator useful in preparing graphene/polyionic liquid composite material for e.g. photovoltaic devices, energy storage batteries and electrochemical sensors.
  • 专利号:   CN108461308-A
  • 发明人:   ZHOU G, SUN X, SI S, GAO T
  • 专利权人:   UNIV QILU TECHNOLOGY
  • 国际专利分类:   B01D053/02, B01J020/26, H01G011/38, H01G011/86
  • 专利详细信息:   CN108461308-A 28 Aug 2018 H01G-011/86 201870 Pages: 8 Chinese
  • 申请详细信息:   CN108461308-A CN10073679 25 Jan 2018
  • 优先权号:   CN10073679

▎ 摘  要

NOVELTY - Pyrane functional group based ring-opening metathesis polymerization initiator i.e. 4-(pyren-1-yl)butyl bicyclo(2.2.1)hept-5-ene-2-carboxylate (I) is new. USE - (I) is useful in preparing graphene/polyionic liquid composite material for capacitors, photovoltaic devices, energy storage batteries and electrochemical sensors, and in antibacterial (all claimed). DETAILED DESCRIPTION - Pyrane functional group based ring-opening metathesis polymerization initiator i.e. 4-(pyren-1-yl)butyl bicyclo(2.2.1)hept-5-ene-2-carboxylate of formula (I) is new. INDEPENDENT CLAIMS are also included for: (1) preparing (I); and (2) preparation of graphene/polyionic liquid composite material, comprising dispersing (I) with graphene in a solvent for a period of time to obtain a initiator-modified graphene, then adding initiator-modified graphene as initiator and Grubbs second generation catalyst as catalyst into polyionic liquid monomer, and carrying out ring-opening metathesis polymerization to obtain final product.