• 专利标题:   Synthesizing hydrogenated methyl nadic anhydride comprises e.g. subjecting dimeric pentamethylcyclopentadiene to pyrolysis and rectification, dropping maleic anhydride, adding ruthenium supported reduced graphene oxide catalyst and reacting.
  • 专利号:   CN108689967-A
  • 发明人:   ZHANG P, FENG H, WU B, ZHANG C, QU F, GAO D, XU J, WANG J, WANG X
  • 专利权人:   PUYANG HUICHENG ELECTRONIC MATERIAL CO
  • 国际专利分类:   C07D307/00, C07D307/93
  • 专利详细信息:   CN108689967-A 23 Oct 2018 C07D-307/00 201880 Pages: 6 Chinese
  • 申请详细信息:   CN108689967-A CN10627288 19 Jun 2018
  • 优先权号:   CN10627288

▎ 摘  要

NOVELTY - Synthesizing hydrogenated methyl nadic anhydride comprises (i) subjecting dimeric pentamethylcyclopentadiene to pyrolysis and rectification at 200-240 degrees C to obtain pentamethylcyclopentadiene, (ii) dropping maleic anhydride into an autoclave containing pentamethylcyclopentadiene at 10-15 degrees C, reacting to form methyl nadic anhydride, and detecting the completion of the reaction by gas chromatography, (iii) adding ruthenium supported reduced graphene oxide catalyst into the autoclave, introducing hydrogen, and reacting at 130-150 degrees C under 5-8 MPa pressure, and (iv) filtering and recycling catalyst when it is hot, and vacuum distilling the liquid phase. USE - The method is useful for synthesizing hydrogenated methyl nadic anhydride. ADVANTAGE - The method: is simple and easy to operate, environmentally friendly and suitable for industrial production; does not generate side reactions, and produces product with purity of more than 98% and yield of more than 90%; and ensures complete utilization of the raw materials.