• 专利标题:   Three-dimensional graphene sponge/ferric oxide composite absorbing material comprises e.g. iron ions, deionized water, spherical popcorn, ferric oxide nanoparticles are uniformly anchors in the three-dimensional graphene sponge structure.
  • 专利号:   CN108774491-A
  • 发明人:   CHEN P, YANG S, YU Q, XIONG X, WANG J
  • 专利权人:   UNIV DALIAN TECHNOLOGY
  • 国际专利分类:   C09K003/00, H05K009/00
  • 专利详细信息:   CN108774491-A 09 Nov 2018 C09K-003/00 201882 Pages: 11 Chinese
  • 申请详细信息:   CN108774491-A CN10794924 19 Jul 2018
  • 优先权号:   CN10794924

▎ 摘  要

NOVELTY - Three-dimensional graphene sponge/ ferric oxide composite absorbing material comprises iron ions, deionized water as a solvent under alkaline conditions, spherical popcorn with a particle size of 150-250 nm, the ferric oxide nanoparticles are uniformly anchors in the three-dimensional graphene sponge structure, where the material is based on a three-dimensional graphene of a mesoporous sponge structure. USE - Used as three-dimensional graphene sponge/ ferric oxide composite absorbing material. ADVANTAGE - The absorbing material has large absorption intensity. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing absorbing material, comprising (i) mixing the nickel powder to the mixed solution of sodium hydroxide solution and polyol, placing into oven , heating to 250-280 degrees C, reacting for 12-15 hours, naturally cooling to the room temperature, washing for many times with deionized water, absolute ethyl alcohol, vacuum drying the product to obtain black powder, adding the black powder into a tubular furnace under the protection of inert atmosphere, heating to 500-800 degrees C for 1-3 hours, naturally cooling to the room temperature, dissolving the nickel nanometer particle core using acid, washing for many times to PH 7 by deionized water, freeze-drying to obtain three-dimensional graphene sponge, adding into deionized water and ultrasonicating to obtain 2-5 mg/ml uniformly dispersed suspension, and adding 20-90 ml polyalcohol to 1-3 g nickel powder, and (ii) adding the three-dimensional graphene sponge suspension obtained in the step (i) into a three-necked flask and mechanically stirring, dissolving iron salt in deionized water to form a yellow solution containing iron oxide, dropping into three-necked flask containing a three-dimensional graphene sponge suspension, and mechanically stirring to obtain a mixed solution, heating to 70-95 degrees C, gradually adding alkaline solution, adjusting the PH of 9 13, reacting for 3-5 hours, using a magnet to adsorb water, alcohol washing to pH 7, and vacuum drying in oven to obtain a product, and adding 0.03-0.15 g three-dimensional graphene sponge/ 0.375-0.625 g iron salt in the mixed solution.