• 专利标题:   Preparation of tungsten nitride nano-needle composite nitrogen-doped graphene nanosheet for lithium-sulfur battery separator, involves mixing tungsten chloride/ethanol solution and graphene oxide dispersion, hydrothermally reacting, and annealing under ammonia atmosphere.
  • 专利号:   CN114014303-A
  • 发明人:   WANG B, ZHANG Z, ZHANG X, MA F, CHEN Y
  • 专利权人:   UNIV CHINA ELECTRONIC SCI TECHNOLOGY
  • 国际专利分类:   B82Y030/00, B82Y040/00, C01B021/06, C01B032/184, H01M010/052, H01M050/403, H01M050/431
  • 专利详细信息:   CN114014303-A 08 Feb 2022 C01B-032/184 202235 Chinese
  • 申请详细信息:   CN114014303-A CN11296260 03 Nov 2021
  • 优先权号:   CN11296260

▎ 摘  要

NOVELTY - Preparation method of tungsten nitride nano-needle composite nitrogen-doped graphene nanosheet, involves dissolving 50-100 mg, preferably 60 mg tungsten chloride powder in 25-40 ml, preferably 30 ml ethanol as solvent to obtain solution (A), ultrasonically dispersing 1-5 mg, preferably 3 mg graphene oxide in 25-40 ml, preferably 30 ml water to obtain solution (B), stir-mixing solutions (A,B) for 0.5 hour at room temperature, adding the mixed solution to a reaction kettle, hydrothermally reacting at 180degrees Celsius for 3-12 hours, collecting the product to obtain a black precursor powder, and annealing the precursor powder at 600degrees Celsius for 2 hours in a tubular furnace under ammonia atmosphere. USE - Preparation of tungsten nitride nano-needle composite nitrogen-doped graphene nanosheet for lithium-sulfur battery separator (all claimed). ADVANTAGE - The tungsten nitride nano-needle composite nitrogen-doped graphene nanosheet separator middle layer prepared as a high-efficiency polysulfide catalyst and adsorbent improves lithium-sulfur battery performance. The method is simple, has good repeatability, is economical, and is feasible. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the tungsten nitride nano-needle composite nitrogen-doped graphene nanosheet.