• 专利标题:   Preparing 4,4',-diaminodicyclohexylmethane, comprises catalytic hydrogenation of 4,4'-diaminodiphenylmethane in presence of graphene-loaded ruthenium catalyst as hydrogenation catalyst, tetrahydrofuran solvent and sodium methoxide.
  • 专利号:   CN113929584-A
  • 发明人:   JIA Y, LI Y, SONG W, WANG C, ZHANG J, WANG L, FU J
  • 专利权人:   JIANGSU QINGQUAN CHEM CO LTD
  • 国际专利分类:   B01J023/46, C07C209/72, C07C211/36
  • 专利详细信息:   CN113929584-A 14 Jan 2022 C07C-209/72 202223 Chinese
  • 申请详细信息:   CN113929584-A CN11382758 22 Nov 2021
  • 优先权号:   CN11382758

▎ 摘  要

NOVELTY - Preparing 4,4',-diaminodicyclohexylmethane (I), comprises catalytic hydrogenation of 4,4'-diaminodiphenylmethane (II) to obtain final product. The content of first isomer of (I) in the product is about 70 wt.%. USE - The method is useful for preparing 4,4',-diaminodicyclohexylmethane. ADVANTAGE - The method utilizes graphene-loaded ruthenium catalyst which has excellent selectivity under the condition of high temperature and high pressure, only a small amount of amino group falls off, and the conversion rate is high. DETAILED DESCRIPTION - Preparing 4,4',-diaminodicyclohexylmethane of formula (I), comprises catalytic hydrogenation of 4,4'-diaminodiphenylmethane of formula (II) to obtain final product. The content of first isomer of (I) in the product is about 70 wt.%.