• 专利标题:   Preparing polycarboxylate aqueous reducing agent using vinyl polyoxyethylene ether comprises adding large monomer, ammonium persulfate and de-ionized water into reactor kettle with stirrer, thermometer and dropping device, stirring, dropping liquids, dropping performance modifier and polymerizing.
  • 专利号:   CN113929343-A, CN113929343-B
  • 发明人:   SUN W
  • 专利权人:   ZHEJIANG HEYE TECHNOLOGY CO LTD
  • 国际专利分类:   C04B103/30, C04B024/32, C08F220/06, C08F283/06
  • 专利详细信息:   CN113929343-A 14 Jan 2022 C04B-024/32 202223 Chinese
  • 申请详细信息:   CN113929343-A CN11244423 26 Oct 2021
  • 优先权号:   CN11244423

▎ 摘  要

NOVELTY - Preparing polycarboxylate aqueous reducing agent using vinyl polyoxyethylene ether comprises (i) adding 100-150 kg large monomer, 0.5-1.5 kg ammonium persulfate and 120-180 kg de-ionized water into the reactor kettle equipped with a stirrer, thermometer and dropping device, and stirring evenly; (ii) dissolving the acrylic acid in de-ionized water to obtain A dropping liquid; (iii) dissolving the vitamin C and sodium hypophosphite in de-ionized water to obtain B dropping liquid; (iv) adding A and B dropping liquid, controlling the dropping time at 60plus minus3 minutes and controlling the reaction temperature at 15plus minus5degrees Celsius; and (v) dropping performance modifier at 12-15 minutes, maintaining the temperature for 1-1.5 hours at 15plus minus5 degrees Celsius to complete polymerization reaction and preserving heat. USE - The method is useful for preparing polycarboxylate aqueous reducing agent using vinyl polyoxyethylene ether. ADVANTAGE - The method: solves the phenomenon that the performance of the polycarboxylic acid is reduced due to excessively high temperature in the traditional method and the phenomenon of over-polymerization to form a gel; produces polycarboxylic acid with improved water reducing rate and slump retention property; saves the production time of the polycarboxylic acid; and improves the production rate.