• 专利标题:   Preparing vanadium sulfide/reduced graphene oxide composite material in anode material of aqueous zinc ion battery by dispersing graphene oxide in deionized water, dissolving vanadium source and sulfur source, dripping aqueous ammonia, reacting, cooling to room temperature, washing and freeze-drying.
  • 专利号:   CN113130863-A
  • 发明人:   LI X, CHEN K, ZHANG L, DAI S, SHAN C
  • 专利权人:   UNIV ZHENGZHOU
  • 国际专利分类:   C01B032/182, H01M010/054, H01M004/36, H01M004/58, H01M004/583, H01M004/62
  • 专利详细信息:   CN113130863-A 16 Jul 2021 H01M-004/36 202173 Pages: 10 Chinese
  • 申请详细信息:   CN113130863-A CN10303802 22 Mar 2021
  • 优先权号:   CN10303802

▎ 摘  要

NOVELTY - Method for preparing vanadium sulfide/reduced graphene oxide composite material, involves (i) dispersing graphene oxide in deionized water to form a graphene oxide solution, where the concentration of the graphene oxide aqueous solution is 0.5-5 mol/ml, (ii) dissolving vanadium source and sulfur source according to molar ratio of vanadium source and sulfur source of (0.6-1.2):(0.6-1.5) in the graphene oxide solution, and stirring to form a uniform premixed solution, (iii) dripping aqueous ammonia to the pre-mixed solution formed in step (ii) under stirring until the pH of the solution is 9 to obtain a mixed solution, (iv) reacting the mixed solution formed in step (iii) at 140-200 degrees C for 24-48 hours, and (v) cooling to room temperature, washing the product and freeze-drying to obtain the vanadium sulfide/reduced graphene oxide composite material. USE - The method is used for preparing vanadium sulfide/reduced graphene oxide composite material in anode material of aqueous zinc ion battery (claimed). ADVANTAGE - The vanadium sulfide/reduced graphene oxide composite material improves capacity, rate performance and cycle stability of the aqueous zinc ion battery. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a vanadium sulfide/reduced graphene oxide composite material prepared by the above method comprising vanadium sulfide particles and reduced graphene oxide, where the vanadium sulfide particles are spherical with a particle size of 200-300 nm, reduced graphene oxide has a three-dimensional network structure, and the vanadium sulfide particles are uniformly attached to the three-dimensional network structure formed by reduced graphene oxide; and (2) the use of the use of the vanadium sulfide/reduced graphene oxide composite material in anode material of an aqueous zinc ion battery.