• 专利标题:   Composite electrode material of sodium titanate nano-fiber/reduction-oxidation graphene, for preparing sodium ion batteries or sodium batteries, comprises two-dimensional sheet layer structure, where particle diameter of particle, thickness, composed of few layers of reducing and oxidizing graphene.
  • 专利号:   CN115642247-A
  • 发明人:   LIU Y, WAN Y, LI W
  • 专利权人:   UNIV FUDAN
  • 国际专利分类:   B82Y030/00, B82Y040/00, C01B032/194, C01G023/00, D01F009/08, H01M010/054, H01M004/485, H01M004/62
  • 专利详细信息:   CN115642247-A 24 Jan 2023 H01M-004/485 202316 Chinese
  • 申请详细信息:   CN115642247-A CN11040452 29 Aug 2022
  • 优先权号:   CN11040452

▎ 摘  要

NOVELTY - Composite electrode material of sodium titanate nano-fiber/reduction-oxidation graphene comprises a two-dimensional sheet layer structure, where the particle diameter of the particle is 1-6 microns, the thickness is 10-20 nm, and it is composed of a few layers of reducing and oxidizing graphene, and the sodium titanate nano-fiber with a diameter of 5-10 nm. USE - Composite electrode material of sodium titanate nano-fiber/reduction-oxidation graphene, for preparing sodium ion batteries or sodium batteries. ADVANTAGE - The material has a simple technique, easy amplification production, and strong controllability, as sodium-ion battery negative electrode or sodium battery positive electrode at the same time with high first-week coulomb efficiency, low working voltage, high capacity, excellent multiplying characteristics, and circulating stability, exhibiting a wide market application prospect. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: 1. a method for preparing composite electrode material of sodium titanate nano-fiber/reduction-oxidation graphene, which involves the synthesis of precursors by using a solvent method: adding a few layers of reduced graphene to the organic solvent with a strong alkali, stirring, and adding titanium source, drying the solvent to obtain the mixture graphene the load titanium dioxide, collecting the precipitate and drying, calcining to obtain rGO/titanium dioxide composite precursor, using hydrothermal treatment method for preparing sodium titanate nano-fiber/reduction-oxidation graphene composite electrode material, the precursor is added to the sodium hydroxide alkali solution, then hydro-thermal treatment, washing and drying to obtain the sodium titanate nano-fiber/reduction-oxidation graphene the composite electrode material; and 2. an application of the composite electrode material of sodium titanate nano-fiber/reduction-oxidation graphene, which comprises for preparing sodium ion batteries or sodium batteries.