• 专利标题:   Preparation of graphene/nanoaluminum oxide composite involves adding aluminum sulfate block to graphite oxide, ball-milling, adding ammonium hydroxide, filtering, calcining graphene oxide/aluminum hydroxide composite, and cooling.
  • 专利号:   CN103723704-A
  • 发明人:   WANG Y, ZHONG H, ZHOU M
  • 专利权人:   OCEANS KING LIGHTING SCI TECHNOLOGY CO, SHENZHEN OCEANS KING LIGHTING ENG CO LTD, SHENZHEN OCEANS KING LIGHTING SCI TECH
  • 国际专利分类:   C01B031/04, C01F007/30
  • 专利详细信息:   CN103723704-A 16 Apr 2014 C01B-031/04 201438 Pages: 7 Chinese
  • 申请详细信息:   CN103723704-A CN10388901 15 Oct 2012
  • 优先权号:   CN10388901

▎ 摘  要

NOVELTY - Aluminum sulfate block is added to graphite oxide in a mass ratio of 1.12-2.51:1, and ball-milled for 5-10 hours. The stoichiometric excess of 30-100 %mass ammonium hydroxide having concentration of 5-10% is added, precipitated, and stirred for 1-4 hours. The resulting mixture is allowed to stand for 24 hours, filtered, filtrate is collected, washed and dried, to obtain graphene oxide/aluminum hydroxide composite. The graphene oxide/aluminum hydroxide composite is calcined in protective gas atmosphere, cooled, and ground, to obtain graphene/nanoaluminum oxide composite. USE - Preparation of graphene/nanoaluminum oxide composite (claimed). ADVANTAGE - The method feasibly and economically provides graphene/nanoaluminum oxide composite having high conductivity, by a simple process. DETAILED DESCRIPTION - Aluminum sulfate block is added to graphite oxide in a mass ratio of 1.12-2.51:1, and ball-milled for 5-10 hours. The stoichiometric excess of 30-100 %mass ammonium hydroxide having concentration of 5-10% is added, precipitated, and stirred for 1-4 hours. The resulting mixture is allowed to stand for 24 hours, filtered, filtrate is collected, washed and dried, to obtain graphene oxide/aluminum hydroxide composite. The graphene oxide/aluminum hydroxide composite is calcined in protective gas atmosphere, cooled, and ground, to obtain graphene/nanoaluminum oxide composite. The content of graphene in graphene/nanoaluminum oxide composite is 40-60 %mass.