• 专利标题:   Catalyst for alkylation of ortho-phenol used for synthesis of o-methylphenol and o-ethylphenol, comprises graphene oxide-containing compound.
  • 专利号:   CN106694037-A, CN106694037-B
  • 发明人:   LIU N, GUAN X, XUE B, LI Y
  • 专利权人:   UNIV CHANGZHOU, UNIV CHANGZHOU
  • 国际专利分类:   B01J021/18, B01J031/02
  • 专利详细信息:   CN106694037-A 24 May 2017 B01J-031/02 201751 Pages: 6 Chinese
  • 申请详细信息:   CN106694037-A CN11106126 06 Dec 2016
  • 优先权号:   CN11106126

▎ 摘  要

NOVELTY - A catalyst comprises graphene oxide-containing compound (I). USE - Catalyst is used for alkylation of ortho-phenol for synthesis of o-methylphenol and o-ethylphenol. ADVANTAGE - The catalyst with catalytic activity of 64% or less, o-alkylphenol selectivity of 79% and excellent stability is prepared by economical method. DETAILED DESCRIPTION - A catalyst comprises graphene oxide-containing compound of formula (I). A=graphene oxide. An INDEPENDENT CLAIM is included for preparation of catalyst, which involves adding graphene oxide to dry toluene such that the mass ratio of graphene and toluene is 1:20-1:50, ultrasonically dispersing mixture, adding 3-aminopropyltrimethoxysilane to reaction system such that the mass ratio of 3-aminopropyltrimethoxysilane and graphene oxide is 1:1-1:5, magnetically stirring mixture at 60-80 degrees C for 10-20 hours, centrifugally separating mixture, washing mixture with deionized water and drying washed product.