• 专利标题:   Preparation of graphene oxide modified pig manure biological carbon used for removing cadmium in sewage by mixing e.g. graphene oxide suspension, polyacrylate and pig manure powder, obtaining composite material, freeze-drying and pyrolyzing.
  • 专利号:   CN108160057-A
  • 发明人:   SONG N, HAN X, LI Y, LIU J, WANG K
  • 专利权人:   UNIV QINGDAO AGRIC
  • 国际专利分类:   B01J020/26, B01J020/30, C02F001/28, C02F101/20
  • 专利详细信息:   CN108160057-A 15 Jun 2018 B01J-020/26 201854 Pages: 11 Chinese
  • 申请详细信息:   CN108160057-A CN10019324 09 Jan 2018
  • 优先权号:   CN10019324

▎ 摘  要

NOVELTY - Preparation of graphene oxide modified pig manure biological carbon comprises adjusting graphene oxide suspension pH value to 5-8 and ultrasonic treating to obtain dispersed single-layered graphene oxide suspension; dropwise adding sodium polyacrylate solution into single-layered graphene oxide suspension to obtain graphene oxide-polyacrylate suspension; mixing pig manure powder with graphene oxide-polyacrylate suspension, stirring for 1-3 hours, standing for 3-4 hours, filtering and collecting precipitate to obtain graphene oxide-modified bio-carbon composite material, where mass-volume ratio of pig manure powder and suspension is 18-22 g:1-1.12 L; washing composite material with water and freeze-drying to obtain primary graphene oxide-modified bio-carbon composite material; removing impurities of primary composite material primary under nitrogen environment, pyrolyzing at 100-400 degrees C for 1-4 hours at 8-15 degrees C/minutes, cooling pyrolysis product, crushing and sieving to obtain product. USE - Method for preparing graphene oxide modified pig manure biological carbon used for removing cadmium in sewage (claimed). ADVANTAGE - The graphene oxide adhered to surface of biochar through sodium polyacrylate forms uneven protrusions, which increased adsorption active sites and improves adsorption efficiency. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for removal of cadmium in sewage comprising adding 0.4-6 g graphene oxide-modified pig manure biochar per liter of wastewater.