• 专利标题:   Anode used in lithium secondary battery, comprises current collector, and located on current collector, anode active material having magnesium-containing silicon oxide, and graphene coating layer, conductive material having single-walled carbon nanotube, and negative electrode active material layer.
  • 专利号:   WO2022060206-A1, KR2022039637-A, EP4195312-A1, CN116235306-A
  • 发明人:   OH I, SHIN S, KIM D, LEE Y, OH I G, SHIN S Y, LEE Y J, LI L, JIN D, SHEN S, WU Y
  • 专利权人:   LG ENERGY SOLUTION LTD, LG ENERGY SOLUTION LTD
  • 国际专利分类:   H01M010/052, H01M004/02, H01M004/131, H01M004/36, H01M004/48, H01M004/62
  • 专利详细信息:   WO2022060206-A1 24 Mar 2022 202228 Pages: 33
  • 申请详细信息:   WO2022060206-A1 WOKR012984 23 Sep 2021
  • 优先权号:   KR121831, CN80064661

▎ 摘  要

NOVELTY - Anode comprises a current collector, and located on at least one surface of the current collector, an anode active material comprising a magnesium-containing silicon oxide, a carbon coating layer surrounding the surface of the magnesium-containing silicon oxide, and a graphene coating layer surrounding the carbon coating layer, a conductive material including single-walled carbon nanotube, and a negative electrode active material layer containing a binder, where the range of the D/G band intensity ratio of the graphene included in the graphene coating layer is 0.8-1.5, and the D/G band intensity ratio of the graphene is defined as the average value of ratio of the maximum peak of the (D) band at 1360 plus minus 50/cm to the maximum peak intensity of the (G) band at 1580 plus minus 50/cm obtained by Raman spectroscopy of graphene. USE - The anode is useful in lithium secondary battery (claimed). ADVANTAGE - The anode has excellent affinity with single-walled carbon nanotubes and excellent flexibility, and prevents electrical short circuit even when silicon oxide shrinks/expands, and ensures excellent shelf life improvement effect, and prevents direct exposure of the magnesium-containing silicon oxide to the electrolyte, prevents the degradation of the magnesium-containing silicon oxide even at high temperature storage, reduces the volume expansion of the magnesium-containing silicon oxide, and exhibits synergistic effects, and improves the shelf life of secondary batteries, and improves high-temperature storage characteristics.