▎ 摘 要
NOVELTY - Method comprises (i) preparing material, (ii) preparing modified water-absorbing material by reacting e.g. tert-butyl hydroperoxide, nitrile rubber, platinum catalyst and hydrogen-containing silicone oil, sieving with 200-mesh sieve to obtain modified water-absorbing material, (iii) preparing water-absorbing microspheres by taking catechol pyrocatechol, hexamethylene, modified water absorbing material, dissolving, stirring to obtain the material B, dissolving anhydrous ethanol, then adding material A, (iv) preparing surface modifying agent by taking phosphoric acid, heating, then adding flame retardant and water absorbing microsphere, stirring to obtain surface modifying agent, (v) taking a base cloth, adding in surface modifying agent, aging and drying to obtain pre-processed base cloth, (vi) taking surface cloth by attaching the surface with thermoplastic elastomer film by hot melt adhesive, pressing and laminating rubber pressing roller, evaporating, curing, heating, and baking. USE - The high fastness elastic jean adhesive surface material is useful in clothes field. ADVANTAGE - The method is simple. The fabric: has flame retardant property, good stiffness, and has high practicability. DETAILED DESCRIPTION - Preparing high fastness elastic jean adhesive surface material comprises (i) preparing material, (ii) preparing modified water-absorbing material by taking tert-butyl hydroperoxide and molybdenum trioxide, mixing and stirring for 15 minutes, heating to 72 degrees C, stirring and reacting for 2.3 hours, reacting, adding nitrile rubber, stirring and reacting at 70 degrees C for 60 minutes, washing with absolute ethyl alcohol, vacuum drying at 40 degrees C to obtain the modified rubber, taking vinyl silicone oil, white carbon black and aluminum hydroxide, mixing and stirring for 3.2 hours, continuously heating to 205 degrees C under the vacuum condition, stirring for 2.1 hours, then adding platinum catalyst and hydrogen-containing silicone oil, continuously stirring for 25 minutes, molding pressing at 143 degrees C for 18 minutes to obtain the silicon rubber, taking nitrile rubber, modified rubber, plasticating for 6 minutes, adding silicon rubber and graphene oxide, mixing for 6 minutes, then orderly adding zinc oxide, stearic acid, anti-aging agent, accelerant, carbon black, sodium polyacrylate and sulfur, mixing for 20 minutes, thinning, vulcanizing at a flat vulcanizing machine for 2.5 minutes at 163 degrees C to obtain the water absorbing material, taking the water absorbing material, dissolving anhydrous ethanol, ultrasonically dispersing for 35 minutes, adding 3-amino propyl trimethoxy siloxane, reacting for 6.1 hours, cooling to room temperature, alcohol washing for 2 times, water washing for 2 times, freezing and drying, grinding, crushing, sieving with 200-mesh sieve to obtain the modified water-absorbing material, (iii) preparing water-absorbing microspheres by taking catechol pyrocatechol, hexamethylene diamine, deionized water to dissolve, stirring for 25 minutes, adding silicon dioxide microsphere, continuously stirring for 15 minutes, reacting for 37 hours at room temperature, centrifuging and separating, washing and placing in the etching liquid, stirring for 30 minutes, centrifuging and separating, washing, vacuum drying at 40 degrees C for 24 hours to obtain the modified microsphere, where the etching liquid comprising hydrofluoric acid and ammonium fluoride in a volume ratio of 1:1, taking modified water absorbing material, dissolving in hydrochloric acid, stirring for 8 minutes, filtering, washing to obtain material A, taking the modified microsphere, dissolving the sodium hydroxide solution, stirring for 8 minutes, filtering, washing to obtain the material B, taking the material B, dissolving anhydrous ethanol, then adding material A, stirring for 15 minutes, filtering, washing, vacuum drying at 40 degrees C to obtain the water absorbing microsphere, (iv) preparing surface modifying agent by taking phosphoric acid, heating to 210 degrees C, reacting for 30 minutes, adding glacial acetic acid and anhydrous piperazine, adjusting the temperature to 113 degrees C for 3.1 hours, filtering, vacuum drying to obtain the flame retardant, taking aluminum chloride hexahydrate, absolute ethyl alcohol, de ionized water and formamide, stirring for 16 minutes, adding tetraethyl orthosilicate, stirring for 25 hours, then adding flame retardant and water absorbing microsphere, continuously stirring for 12 minutes, then adding 1, 2-propylene oxide, stirring for 4.5 minutes to obtain the surface modifying agent, (v) taking a base cloth, washing with anhydrous ether for 5.5 hours, cleaning with deionized water, drying and placing in sodium hydroxide solution, soaking for 0.9 hours, washing with deionized water, drying, then adding in the surface modifying agent, soaking for 4 minutes, taking out the base cloth, allowing to stand for 22 hours at room temperature, aging and drying to obtain the pre- processed base cloth, (vi) taking the surface cloth by attaching the surface with thermoplastic elastomer film by hot melt adhesive, pressing the rubber pressing roller, evaporating and curing for 43 hours to obtain the pre-processed surface cloth, then taking the pre-processing base cloth, attaching the pre-processing surface cloth to the surface of the pre-processing base cloth, pressing and laminating the rubber pressing roller, evaporating and curing for 42 hours, then drying for 35 seconds at 110 degrees C, heating to 150 degrees C, baking for 2.5 minutes to obtain adhesive fabric, where the surface modifying agent comprising 6 pts. wt. flame retardant, 11 pts. wt. water absorbing microsphere, 9 pts. wt. aluminum chloride hexahydrate, 28 pts. wt. absolute ethyl alcohol, 5 pts. wt. formamide, 5 pts. wt. tetraethyl orthosilicate, 12 pts. wt. 1, 2-propylene oxide, and water-absorbing material comprising 95 pts. wt. nitrile rubber, 35 pts. wt. modified rubber, 25 pts. wt. silicon rubber, 7 pts. wt. graphene oxide, 4.5 pts. wt. zinc oxide, 1.5 pts. wt. stearic acid, 2.5 pts. wt. anti-aging agent, 3.5 pts. wt. accelerator, 9 pts. wt. carbon black, 32 pts. wt. sodium polyacrylate, 2.5 pts. wt. sulfur, and the grain diameter of the silicon dioxide microsphere is 0.09 mm.