• 专利标题:   Preparation of highly ordered mesoporous graphene material, involves cracking of oleic acid precursor of iron, dissolving iron oxide nanoparticles coated with oleic acid molecule in n-hexane and distilling off n-hexane and calcining.
  • 专利号:   CN104860306-A, CN104860306-B
  • 发明人:   DING Y, HE G, JIAO Y, LI N, DONG A
  • 专利权人:   HAIMEN RONGHUI GEN LITHIUM IND CO LTD, JIANGSU RONGHUI GEN LITHIUM IND CO LTD
  • 国际专利分类:   C01B031/04, C01B032/184
  • 专利详细信息:   CN104860306-A 26 Aug 2015 C01B-031/04 201617 Pages: 10 Chinese
  • 申请详细信息:   CN104860306-A CN10233800 19 Jun 2015
  • 优先权号:   CN10233800

▎ 摘  要

NOVELTY - The preparation method of highly ordered mesoporous graphene material, involves performing high-temperature cracking of oleic acid precursor nanoparticles of iron, to obtain iron oxide nanoparticles coated with oleic acid molecule, dissolving nanoparticles in n-hexane, distilling off n-hexane to obtain nanoparticle array structure, calcining with nitrogen or argon gas, to obtain iron oxide nanoparticles coated with carbon layer, acid etching to obtain mesoporous carbon material, and performing graphitization. USE - Preparation of highly ordered mesoporous graphene material, which is useful in drug-loading, waste water treatment and energy storage. ADVANTAGE - The method enables preparation of highly ordered mesoporous graphene material in simple and economical manner with different diameter and shape. DETAILED DESCRIPTION - The preparation method of highly ordered mesoporous graphene material, involves performing high-temperature cracking of oleic acid precursor nanoparticles of iron under the action of high boiling solvent to obtain iron oxide nanoparticles coated with oleic acid molecule, dissolving nanoparticles in n-hexane, distilling off n-hexane to obtain highly ordered nanoparticle array structure, calcining highly ordered nanoparticle array structure with nitrogen or argon gas at 300 degrees C for carbonization of oleic acid molecule on surface to obtain nanoparticles with carbon layer coating, acid etching to obtain mesoporous carbon material having high specific surface area, and performing graphitization of mesoporous carbon material. The high-boiling solvent is hexadecene, octyl ether, octadecene or eicosene, and acid used for acid etching is hydrochloric acid, sulfuric acid or nitric acid.