• 专利标题:   Preparing doped reduced graphene oxide, by preparing intermediate product by processing solution comprising partially reduced graphene oxide and ionic liquid comprising cation containing nitrogen, phosphorus or sulfur followed by annealing.
  • 专利号:   KR2015020156-A, KR1760321-B1
  • 发明人:   LEE H
  • 专利权人:   UNIV SUNGKYUNKWAN RES BUSINESS FOUND
  • 国际专利分类:   B01J019/10, C01B031/04
  • 专利详细信息:   KR2015020156-A 25 Feb 2015 C01B-031/04 201523 Pages: 22
  • 申请详细信息:   KR2015020156-A KR191778 29 Dec 2014
  • 优先权号:   KR097490, KR191778

▎ 摘  要

NOVELTY - Preparing nitrogen-, phosphorus- or sulfur-doped reduced graphene oxide, involves: (a) preparing an intermediate product of reduced graphene oxide by processing a solution comprising partially reduced graphene oxide and an ionic liquid comprising a cation containing nitrogen, phosphorus or sulfur; (b) annealing the intermediate product; (c) heating the product and then performing co-evaporation; (d) performing thermal reduction of the mixture to obtain reduced graphene oxide; and (e) partly substituting nitrogen-, phosphorus-, or sulfur-atom to be doped on the obtained reduced graphene oxide. USE - The method is useful for preparing nitrogen-, phosphorus- or sulfur-doped reduced graphene oxide (claimed), which is useful for semiconductor devices. ADVANTAGE - The method is capable of eco-friendly preparing the nitrogen-, phosphorus- or sulfur-doped reduced graphene oxide with improved nonflammability and thermal stability using the cost-effective ionic liquid. DETAILED DESCRIPTION - Preparing nitrogen-, phosphorus- or sulfur-doped reduced graphene oxide, comprises: (a) preparing an intermediate product of reduced graphene oxide by processing a solution comprising partially reduced graphene oxide and an ionic liquid comprising a cation containing nitrogen, phosphorus or sulfur; (b) annealing the intermediate product of reduced graphene oxide; (c) heating the annealed product and then performing co-evaporation with a solvent having high boiling point; (d) performing thermal reduction of the mixture to obtain reduced graphene oxide; and (e) partly substituting nitrogen-, phosphorus-, or sulfur-atom to be doped on the obtained reduced graphene oxide.