• 专利标题:   Making high-strength composite comprises e.g. plating conducting surface on substrate, electroplating flat graphene flakes onto surface from carrier fluid suspension of graphene flakes, removing plated substrate from vessel and drying.
  • 专利号:   WO2013062951-A1, WO2013062951-A4, CA2853670-A1, EP2771395-A1, KR2014105442-A, US2014299475-A1, KR1625311-B1, CA2853670-C, EP2771395-B1, EP2771395-A4, EP2771395-B8, EP3266814-A1, US9951436-B2, US2018195198-A1, EP3266814-B1
  • 发明人:   BULLINGTON J A, STOLTZ R A, BULLINGTON J, STOLTZ R
  • 专利权人:   GARMOR INC, GARMOR INC, GARMOR INC, GARMOR INC
  • 国际专利分类:   B82B003/00, C01B031/02, C08K003/04, C08L055/02, C08L063/00, C08J003/20, C25D015/00, B82Y030/00, C09D155/02, C09D007/00, C25D013/04, C09D007/20
  • 专利详细信息:   WO2013062951-A1 02 May 2013 C08K-003/04 201333 Pages: 19 English
  • 申请详细信息:   WO2013062951-A1 WOUS061457 23 Oct 2012
  • 优先权号:   US551983P, US14353760, CA2853670, KR714095, US914173

▎ 摘  要

NOVELTY - Making (M1) high-strength composite, comprises: plating conducting surface on substrate; electroplating flat graphene flakes onto conducting surface from carrier fluid suspension of graphene flakes in vessel to give plated layer; (b) drying to remove carrier fluid from plated graphene; (c) applying layer of polymer containing solvent to infiltrate between graphene flakes, where the polymer is chemically bondable to graphene, and the solvent containing polymer has viscosity of 1-30000 centipoises; and removing air from between graphene flakes infiltrated by bondable polymer layer. USE - The method is useful for making a high-strength composite which is used as fiber, yarn rope of cable, sheet or layer (claimed). ADVANTAGE - The method provides composite which has high-strength (claimed) and is lighter. DETAILED DESCRIPTION - Making (M1) a high-strength composite, comprises: plating a conducting surface on a substrate; electroplating flat graphene flakes onto the conducting surface from a carrier fluid suspension of graphene flakes in a vessel to give a plated layer, where the flakes have an average width of 0.5-100 microns; (a) removing the plated substrate from the vessel; (b) drying to remove carrier fluid from the plated graphene; (c) applying a layer of polymer containing a solvent to infiltrate between the graphene flakes, where the polymer is chemically bondable to the graphene, and the solvent containing polymer has a viscosity of 1-30000 centipoises; and removing air from between the graphene flakes infiltrated by the bondable polymer layer. INDEPENDENT CLAIMS are also included for: (1) making a high-strength composite, comprising plating a nickel surface on a substrate, electroplating flat graphene flakes onto the conducting surface from a water suspension of graphene flakes in a vessel to give a plated layer, where the flakes are 5-20 micron across, steps (a)-(c) as above per se, and removing solvent from the polymer and air from between the graphene flakes infiltrated by the bondable polymer layer; and (2) a high-strength composite made by the method (M1) and comprising flat graphene flakes disposed on an electroplated layer formed on a substrate, and a polymer chemically bonding at least one of in, about, or to the graphene.