• 专利标题:   Forming reduced graphene oxide/metal sulfide composite, useful as anode in e.g. lithium ion battery, comprises e.g. adding dispersion of graphene oxide to hydrogen peroxide solution, and adding metal complex or salt solution to dispersion.
  • 专利号:   WO2014081389-A1, US2015318544-A1, US9755227-B2
  • 发明人:   YU Y W D, BATABYAL S K, LEV O, GUN J, PRIKHODCHENKO P V
  • 专利权人:   UNIV NANYANG TECHNOLOGICAL, YISSUM RES DEV CO HEBREW UNIV JERUSALEM, YU Y W D, BATABYAL S K, LEV O, GUN J, PRIKHODCHENKO P V
  • 国际专利分类:   B82Y030/00, B82Y040/00, C01B031/04, H01M010/0525, H01M010/054, H01M004/36, H01M004/48, H01M004/58, C01B017/20, C01G001/12, C01G019/00, C01G030/00, H01B001/04, H01M004/136, H01M004/62
  • 专利详细信息:   WO2014081389-A1 30 May 2014 C01B-031/04 201438 Pages: 59 English
  • 申请详细信息:   WO2014081389-A1 WOSG000488 15 Nov 2013
  • 优先权号:   US728572P, US814582P, US14646261

▎ 摘  要

NOVELTY - Forming a reduced graphene oxide/metal sulfide composite, comprises: adding a dispersion comprising graphene oxide to hydrogen peroxide solution; adding at least one metal complex or salt solution to the dispersion; precipitating at least one peroxide-rich sol onto the graphene oxide surface to form at least one more peroxide rich-metal oxide precursor-supported graphene oxide; treating the supported graphene oxide with a sulfur source; heating the treated supported graphene oxide at a first temperature to form a powder; and heating the powder at a second temperature to form the composite. USE - The method is useful for forming reduced graphene oxide/metal sulfide composite, which useful as an anode in a lithium ion or sodium ion battery (claimed). ADVANTAGE - The method: provides the reduced graphene oxide/metal sulfide composite, which is free from agglomerates of metal sulfide particles, and exhibits excellent rate capability, charging rate and cycle stability as anode material; and does not require sophisticated equipment or an autoclave, hence it is cost effective, as compared to conventional methods. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a reduced graphene oxide/metal sulfide composite formed by the method.