• 专利标题:   Manufacture of three-dimensional porous graphene-loaded carbon-coated lithium sulfide material used for cathode, involves calcining precursor obtained from three-dimensional porous graphene solution, lithium sulfate and carbon material.
  • 专利号:   CN105406034-A
  • 发明人:   GU Z, TU J, WANG X, XIA X, WANG D
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/58, H01M004/62
  • 专利详细信息:   CN105406034-A 16 Mar 2016 H01M-004/36 201649 Pages: 10 English
  • 申请详细信息:   CN105406034-A CN10705408 27 Oct 2015
  • 优先权号:   CN10705408

▎ 摘  要

NOVELTY - Manufacture of three-dimensional porous graphene-loaded carbon-coated lithium sulfide cathode material involves dispersing graphene oxide in water, magnetically-stirring, ultrasonically-treating to obtain graphene oxide solution, adding reducing agent to the solution to obtain brown solution, transferring the brown solution into autoclave, hydrothermally-reacting, cooling to obtain a three-dimensional porous graphene solution, mixing three-dimensional porous graphene solution, lithium sulfate and carbon material, stirring, freeze-drying to obtain precursor, and calcining the precursor. USE - Manufacture of three-dimensional porous graphene-loaded carbon-coated lithium sulfide material used for cathode of battery (all claimed). ADVANTAGE - The method enables efficient manufacture of three-dimensional porous graphene-loaded carbon-coated lithium sulfide material with high productivity and excellent electrical properties, by simple method. DETAILED DESCRIPTION - Manufacture of three-dimensional porous graphene-loaded carbon-coated lithium sulfide cathode material involves dispersing graphene oxide in water, magnetically-stirring, ultrasonically-treating to obtain graphene oxide solution, adding a reducing agent to the solution to obtain a brown solution, transferring the brown solution into the autoclave, sealing the autoclave, hydrothermally-reacting at 120-200 degrees C for 4-12 hours, cooling to obtain a three-dimensional porous graphene solution, mixing three-dimensional porous graphene solution, lithium sulfate and carbon material, stirring, freeze-drying to obtain a precursor, and calcining the precursor at 800-1000 degrees C for 2-12 hours.